Complexes of Ag, Cu, Ca, Nd, and Er nitrates with 4′-nitrobenzo-15-crown-5 (NB15C5) were synthesized and their IR absorption spectra were studied. Macrocyclic conformation in the complexes was determined. The structures of the complexes were proposed with account of the data of IR absorption spectra and of the previous X-ray diffraction study. In the Ag, Cu, and Ca complexes, NB15C5 was found in the inner sphere, while in the Nd and Er complexes, it was found to be the outer-sphere ligand.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Kireeva, I.K., Generalova, N.B., Trofimov, V.A., and Tsivadze, A.Yu., Zh. Neorg. Khim., 1991, vol. 36,no. 6, p. 1464.
Roders, R.O., Henry, R.F., and Rollins, A.N., J. Incl. Mol. Recogn. Chem., 1992, no. 19, p. 219.
Hanson, I.R., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1978, vol. 34,no. 3, p. 1026.
Roders, R.O., Hugins, S.E., Henry, R.F., et al., Supramol. Chem., 1992, no. 1, p. 59.
Minacheva, L.Kh., Ivanova, I.S., Kamalov, Zh.K., et al., Dokl. Akad. Nauk, 1999, vol. 268,no. 5, p. 632.
Matlinson, P.R. and Truter, M.R., J. Chem. Soc., Perkin Trans. 2, 1972, no. 12, p. 1818.
Owen, J.D., J. Chem. Soc., Dalton Trans., 1980, no. 7, p. 1066.
Bush, M.A. and Truter, M.R., J. Chem. Soc., Perkin Trans. 2, 1972, no. 3, p. 341.
Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, London: Methuen, 1959.
About this article
Cite this article
Ivanova, I.S., Kireeva, I.K., Dorokhov, A.V. et al. Complexes of Some Metal Nitrates with 4′-Nitrobenzo-15-Crown-5. Russian Journal of Coordination Chemistry 30, 425–429 (2004). https://doi.org/10.1023/B:RUCO.0000030164.02035.6c
- Physical Chemistry
- Absorption Spectrum
- Diffraction Study
- Metal Nitrate