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Synthesis, Crystal Structure, and Properties of Mixed Salt Cs2SO4 · H6TeO6

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Abstract

Mixed salt Cs2SO4 · H6TeO6 (I) is synthesized and its structure and properties are studied by X-ray diffraction analysis, IR and Raman spectroscopies, impedance measurements, and differential thermal analysis. Compound I crystallizes in hexagonal system with unit cell parameters a = 7.455(1) Å, c = 33.303(7) Å, space group R3c, Z = 6. Its crystal structure consists of the H6TeO6 molecules and SO4 2- anions united by network of hydrogen bonds and Cs+ cations.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    E. V. Romanchenko, G. V. Shilov, Yu. A. Dobrovolskii, A. I. Karelin & L. O. Atovmyan

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  1. E. V. Romanchenko
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  2. G. V. Shilov
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  3. Yu. A. Dobrovolskii
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  4. A. I. Karelin
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  5. L. O. Atovmyan
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Romanchenko, E.V., Shilov, G.V., Dobrovolskii, Y.A. et al. Synthesis, Crystal Structure, and Properties of Mixed Salt Cs2SO4 · H6TeO6 . Russian Journal of Coordination Chemistry 30, 301–306 (2004). https://doi.org/10.1023/B:RUCO.0000025996.67107.04

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  • DOI: https://doi.org/10.1023/B:RUCO.0000025996.67107.04

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