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New unsymmetrical salen-type ligand from enantiomerically pure 2-hydroxypinan-3-one

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Abstract

The reaction of enantiomerically pure (–)-2-hydroxypinan-3-one with ethylenediamine was studied. Depending on the reagent ratio, the reaction can afford either mono- or bis-Schiff"s bases. The enantiomerically pure unsymmetrical terpenoid salen-type ligand was prepared by the reaction of 3-[(2-aminoethyl)imino]pinan-2-ol with salicylaldehyde.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Science Center, Ural Branch of the Russian Academy of Sciences, 48 ul. Pervomaiskaya, 167982 Syktyvkar, Russian Federation, Russia

    I. A. Dvornikova, L. L. Frolova & A. V. Kuchin

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation, Russia

    A. V. Churakov

Authors
  1. I. A. Dvornikova
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  2. L. L. Frolova
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  3. A. V. Churakov
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  4. A. V. Kuchin
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Dvornikova, I.A., Frolova, L.L., Churakov, A.V. et al. New unsymmetrical salen-type ligand from enantiomerically pure 2-hydroxypinan-3-one. Russian Chemical Bulletin 53, 1323–1326 (2004). https://doi.org/10.1023/B:RUCB.0000042294.94599.ce

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  • DOI: https://doi.org/10.1023/B:RUCB.0000042294.94599.ce

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