Abstract
New calix[4]arenes, di- and tetrasubstituted at the lower rim, with different functional groups were synthesized. They were studied as carriers of a series of dicarboxylic and α-hydroxycarboxylic acids through a liquid impregnated membrane. The calix[4]arenes under study are capable of molecular recognition of oxalic acid in the series of structurally similar dicarboxylic and α-hydroxycarboxylic acids. The regularities found make it possible to change purposefully the receptor ability of 1,3-disubstituted calix[4]arenes by variation of the nature of substituents.
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Stoikov, I.I., Gafiullina, L.I., Ibragimova, D.S. et al. Synthetic receptors based on calix[4]arene functionalized at the lower rim in molecular recognition of dicarboxylic, α-hydroxycarboxylic, and α-amino acids. Russian Chemical Bulletin 53, 1172–1180 (2004). https://doi.org/10.1023/B:RUCB.0000042270.26330.cb
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DOI: https://doi.org/10.1023/B:RUCB.0000042270.26330.cb