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Alkylation of carboxylic acid derivatives with dialkoxytitanacyclopropane reagents

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Russian Chemical Bulletin Aims and scope

Abstract

Methods for the generation of dialkoxytitanacyclopropanes (dialkoxytitanium olefin complexes) are surveyed. Alkylation of carboxylic acid derivatives with these reagents giving rise to β-titanio ketones and related species, which are spontaneously transformed into the corresponding cyclopropane compounds or react with external electrophiles, are considered.

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Kulinkovich, O.G. Alkylation of carboxylic acid derivatives with dialkoxytitanacyclopropane reagents. Russian Chemical Bulletin 53, 1065–1086 (2004). https://doi.org/10.1023/B:RUCB.0000041303.52400.ca

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