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Synthesis and properties of optically active ferrocenylethylindazoles

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Abstract

The stereochemistry of two processes, viz., α-ferrocenylalkylation of indazole with optically active S-(+)-1-ferrocenylethanol and the thermal rearrangement of S-(+)-2-N-(ferrocenylethyl)indazole into S-(+)-1-N-(ferrocenylethyl)indazole, was studied. Both reactions proceed stereoselectively.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Simenel, Yu. V. Kuzmenko, M. M. Ilyin, V. V. Gumenyuk, L. V. Snegur & Yu. S. Nekrasov

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  1. A. A. Simenel
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  2. Yu. V. Kuzmenko
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  3. M. M. Ilyin
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  4. V. V. Gumenyuk
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  5. L. V. Snegur
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  6. Yu. S. Nekrasov
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Simenel, A.A., Kuzmenko, Y.V., Ilyin, M.M. et al. Synthesis and properties of optically active ferrocenylethylindazoles. Russian Chemical Bulletin 53, 939–941 (2004). https://doi.org/10.1023/B:RUCB.0000037868.08052.23

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  • DOI: https://doi.org/10.1023/B:RUCB.0000037868.08052.23

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