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Organometallic synthesis in the furazan series. 4. Reactions of azofurazans with organolithium compounds

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Abstract

The reactions of azofurazans, including macrocyclic azofurazans, with BunLi and Li derivatives of methylfurazans were studied. Several competitive processes were found to occur: the addition of a Li reagent at the N=N bond, the redox reaction giving rise to hydrazofurazans, and the reaction of the side chain of azofurazan.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. B. Sheremetev, E. A. Ivanova, E. V. Shatunova & D. E. Dmitriev

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. E. Kuz"mina

Authors
  1. A. B. Sheremetev
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  2. E. A. Ivanova
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  3. E. V. Shatunova
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  4. D. E. Dmitriev
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  5. N. E. Kuz"mina
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Sheremetev, A.B., Ivanova, E.A., Shatunova, E.V. et al. Organometallic synthesis in the furazan series. 4. Reactions of azofurazans with organolithium compounds. Russian Chemical Bulletin 53, 615–621 (2004). https://doi.org/10.1023/B:RUCB.0000035645.16537.ea

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  • DOI: https://doi.org/10.1023/B:RUCB.0000035645.16537.ea

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