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Reaction of chloromercuriocobaltacarborane with derivatives of the undecaborate anion

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Abstract

The reactions of the undecaborate anion Cs+C2B9H12 – (1) and exo-nido-ruthenacarborane exo-nido-5,6,10-[Cl(Ph3P)2Ru]-5,6,10-(μ-H)3-10-H-7,8-C2B9H8 (2) with the 9-chloromercurated cobaltacarborane, viz., 3-(η5-Cp)-9-ClHg-3,1,2-CoC2B9H10 (3), afforded Cs[10-{3"-(η5-Cp)-3",1",2"-CoC2B9H10-9"-Hg}-7,8-C2B9H11] (4) and 5,6,10-exo-nido-[Cl(Ph3P)2Ru]-5,6,10-(μ-H)3-10-{3"-(η5-Cp)-3",1",2"-CoC2B9H10-9"-Hg}-7,8-C2B9H8 (5), respectively. The latter compound exists as two isomers. Compound 5 was prepared also by the reaction of compound 4 with Ru(PPh3)3Cl2.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. A. Lobanova, O. M. Khitrova, P. V. Petrovskii & V. I. Bregadze

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  1. I. A. Lobanova
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  2. O. M. Khitrova
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  3. P. V. Petrovskii
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  4. V. I. Bregadze
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Lobanova, I.A., Khitrova, O.M., Petrovskii, P.V. et al. Reaction of chloromercuriocobaltacarborane with derivatives of the undecaborate anion. Russian Chemical Bulletin 53, 251–253 (2004). https://doi.org/10.1023/B:RUCB.0000024858.19814.5a

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  • DOI: https://doi.org/10.1023/B:RUCB.0000024858.19814.5a

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