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Complexes of CuII, NiII, and CoII with 2-cyano-2-(1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl)-1-R-ethylenolates

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Abstract

Copper(ii), nickel(ii), and cobalt(ii) complexes with deprotonated enaminoketone derivatives of 2-imidazoline nitroxide were synthesized. Their crystal structures were established by X-ray diffraction analysis, and their magnetic properties were investigated. All complexes exhibit strong (40—110 cm–1) intramolecular ferromagnetic exchange interactions.

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References

  1. V. I. Ovcharenko and R. Z. Sagdeev, Usp. Khim., 1999, 68, 381 [Russ. Chem. Rev., 1999, 68, 243 (Engl. Transl.)].

    Google Scholar 

  2. R. N. Musin, P. V. Schastnev, and S. A. Malinovskaya, Inorg. Chem., 1992, 31, 4118.

    Google Scholar 

  3. V. I. Ovcharenko, A. B. Burdukov, and R. N. Musin, Mol. Cryst. Liq. Cryst., 1995, 273, 89.

    Google Scholar 

  4. R. N. Musin, I. V. Ovcharenko, L. Ohrstrom, and P. Rey, Zh. Strukt. Khim., 1997, 38, 840 [Russ. J. Struct. Chem., 1997, 38, 703 (Engl. Transl.)].

    Google Scholar 

  5. R. N. Musin, I. V. Ovcharenko, L. Ohrstrom, and P. Rey, Zh. Strukt. Khim., 1997, 38, 850 [Russ. J. Struct. Chem., 1997, 38, 711 (Engl. Transl.)].

    Google Scholar 

  6. V. I. Ovcharenko, G. V. Romanenko, I. V. Korobkov, V. N. Ikorskii, I. V. Ovcharenko, R. N. Musin, K. E. Vostrikova, A. V. Podoplelov, O. V. Shishkin, and Yu. T. Struchkov, Zh. Strukt. Khim., 1998, 39, 901 [Russ. J. Struct. Chem., 1998, 39, 734 (Engl. Transl.)].

    Google Scholar 

  7. P. A. Petrov, S. V. Fokin, G. V. Romanenko, Y. G. Shvedenkov, V. A. Reznikov, and V. I. Ovcharenko, Mendeleev Commun., 2001, 179.

  8. A. G. Orpen, L. Brammer, F. H. Allen, O. Kennard, D. G. Watson, and R. Taylor, J. Chem. Soc., Dalton Trans., 1989, S1.

  9. O. V. Koreneva, G. V. Romanenko, V. N. Ikorskii, S. V. Fokin, and V. I. Ovcharenko, Zh. Strukt. Khim., 2001, 42, 977 [Russ. J. Struct. Chem., 2001, 42 (Engl. Transl.)].

    Google Scholar 

  10. C. Hirel, D. Luneau, J. Pecaut, L. Ohrstrom, G. Bussiere, and C. Reber, Chem. A Eur. J., 2002, 8, 3157.

    Google Scholar 

  11. S. V. Fokin, G. V. Romanenko, Yu. G. Shvedenkov, V. N. Ikorskii, S. F. Vasilevskii, E. V. Tret'yakov, and V. I. Ovcharenko, Zh. Strukt. Khim., 2002, 43, 891 [Russ. J. Struct. Chem., 2002, 43 (Engl. Transl.)].

    Google Scholar 

  12. A. B. Burdukov, D. A. Guschin, N. V. Pervukhina, V. N. Ikorskii, Yu. G. Shvedenkov, V. A. Reznikov, and V. I. Ovcharenko, Crystal Eng., 1999, 2, 265.

    Google Scholar 

  13. A. B. Burdukov, D. A. Guschin, V. A. Reznikov, N. V. Pervukhina, Yu. A. Gatilov, T. V. Rybalova, and V. I. Ovcharenko, Challenges for Coordination Chemistry in the New Century, Eds. M. Melnik and A. Sirota, Slovak Technical University Press, Bratislava, 2001, 5, 121.

    Google Scholar 

  14. F. Lanfranc de Panthou, D. Luneau, R. Musin, L. Ohrstrom, A. Grand, P. Turek, and P. Rey, Inorg. Chem., 1996, 35, 3484.

    Google Scholar 

  15. I. V. Ovcharenko, Yu. G. Shvedenkov, R. N. Musin, and V. N. Ikorskii, Zh. Strukt. Khim., 1999, 40, 36 [Russ. J. Struct. Chem., 1999, 40, 29 (Engl. Transl.)].

    Google Scholar 

  16. J. A. Bertrand and R. I. Kaplan, Inorg. Chem., 1966, 5, 489.

    Google Scholar 

  17. A. J. Gordon and R. A. Ford, The Chemist's Companion, Wiley, New York-London-Sydney-Toronto, 1972.

    Google Scholar 

  18. G. M. Sheldrick, SHELX97. Release 97-2, University of Göttingen, Göttingen (Germany), 1998.

    Google Scholar 

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    P. A. Petrov, G. V. Romanenko, V. I. Ovcharenko & R. Z. Sagdeev

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    Yu. G. Shvedenkov & V. N. Ikorskii

  3. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    V. A. Reznikov

Authors
  1. P. A. Petrov
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  2. G. V. Romanenko
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  3. Yu. G. Shvedenkov
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  4. V. N. Ikorskii
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  5. V. I. Ovcharenko
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  6. V. A. Reznikov
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  7. R. Z. Sagdeev
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Petrov, P.A., Romanenko, G.V., Shvedenkov, Y.G. et al. Complexes of CuII, NiII, and CoII with 2-cyano-2-(1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl)-1-R-ethylenolates. Russian Chemical Bulletin 53, 99–108 (2004). https://doi.org/10.1023/B:RUCB.0000024836.23456.a8

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  • DOI: https://doi.org/10.1023/B:RUCB.0000024836.23456.a8

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