Abstract
The ruthenium complexes with tetra-15-crown-5-phthalocyanine and various axial ligands were synthesized and characterized by spectroscopy. A method for the synthesis of bisaxially coordinated ruthenium(ii) tetra-15-crown-5-phthalocyaninates with the N-donor ligands (R4Pc)Ru(L2) (R4Pc2– = [4,5,4",5",4″,5″,4‴,5‴-tetrakis(1,4,7,10,13-pentaoxotridecamethylene)phthalocyaninate-ion], L is trimethylamine (Me3N), pyridine (py), isoquinoline (iqnl), triethylamine (Et3N), pyrazine (pyz)) was developed. The preparation technique involves selective decarbonylation of (R4Pc)Ru(CO)(MeOH) on treatment with Me3NO in excess N-donor solvent.
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Gorbunova, Y.G., Enakieva, Y.Y., Sakharov, S.G. et al. Ruthenium(ii) complexes with tetra-15-crown-5-phthalocyanine: synthesis and spectroscopic investigation. Russian Chemical Bulletin 53, 74–79 (2004). https://doi.org/10.1023/B:RUCB.0000024832.76270.94
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DOI: https://doi.org/10.1023/B:RUCB.0000024832.76270.94