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Unusual transformations of polynuclear cobalt trimethylacetate complex in tetrahydrofuran on exposure to atmospheric oxygen. Synthesis and structure of the cobalt(iii) complexes [Co6(μ4-O)2(μ3-OH)2(OH)2(μ-OOCBut)9]+(OOCBut)–(HOOCBut) and Co14(μ5-O)2(μ3-O)2(μ3-OH)12(OH)4(μ-OOCBut)8(OOCBut)10·2[OC(=O)C3H6]·2[OC(H)(OH)C3H6]

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    T. O. Denisova, M. A. Golubnichaya & S. E. Nefedov

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  1. T. O. Denisova
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  2. M. A. Golubnichaya
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  3. S. E. Nefedov
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Denisova, T.O., Golubnichaya, M.A. & Nefedov, S.E. Unusual transformations of polynuclear cobalt trimethylacetate complex in tetrahydrofuran on exposure to atmospheric oxygen. Synthesis and structure of the cobalt(iii) complexes [Co6(μ4-O)2(μ3-OH)2(OH)2(μ-OOCBut)9]+(OOCBut)–(HOOCBut) and Co14(μ5-O)2(μ3-O)2(μ3-OH)12(OH)4(μ-OOCBut)8(OOCBut)10·2[OC(=O)C3H6]·2[OC(H)(OH)C3H6]. Russian Chemical Bulletin 52, 2760–2763 (2003). https://doi.org/10.1023/B:RUCB.0000019900.35162.ab

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  • DOI: https://doi.org/10.1023/B:RUCB.0000019900.35162.ab

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