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Synthesis and structure of new dinuclear palladium complex containing no bridging ligands

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Abstract

Oxidation of the mononuclear semiquinonediimine complex [(NPh)(NH)C6H4]2Pd with silver trifluoromethanesulfonate afforded the diamagnetic dinuclear dicationic palladium complex {[(NPh)(NH)C6H4]2Pd}2(O3SCF3)2 with a Pd...Pd distance of 3.267(1) Å. The complex was structurally characterized, and its spectroscopic and electrochemical properties were studied.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. O. Talismanova, I. G. Fomina, A. A. Sidorov, G. G. Aleksandrov, I. F. Golovaneva, I. L. Eremenko & I. I. Moiseev

  2. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation

    N. T. Berberova, A. O. Okhlobystin & E. V. Shinkar"

Authors
  1. M. O. Talismanova
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  2. I. G. Fomina
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  3. A. A. Sidorov
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  4. G. G. Aleksandrov
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  5. N. T. Berberova
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  6. A. O. Okhlobystin
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  7. E. V. Shinkar"
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  8. I. F. Golovaneva
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  9. I. L. Eremenko
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  10. I. I. Moiseev
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Talismanova, M.O., Fomina, I.G., Sidorov, A.A. et al. Synthesis and structure of new dinuclear palladium complex containing no bridging ligands. Russian Chemical Bulletin 52, 2701–2706 (2003). https://doi.org/10.1023/B:RUCB.0000019889.86122.91

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  • DOI: https://doi.org/10.1023/B:RUCB.0000019889.86122.91

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