Skip to main content
SpringerLink
Log in

Spin-adducts of radicals ·P(O)(OPri)2 and ·CMe3 with pyrrolidino[60]fullerenes studied by ESR spectroscopy

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The addition of the ·But (R1) and ·P(O)(OPri)2 (R2) radicals to pyrrolidino[60]fullerenes C60CH2NMeCHX (X = C6H4N(CH2CH2Cl)2, 2,6-(But)2C6H2OH, PhC6H4, and indol-3-yl) was studied by ESR spectroscopy. The rate constants of R1 radical addition to these compounds and dimerization of spin-adducts of the R1 radicals with pyrrolidino[60]fullerenes were determined. Pyrrolidino[60]fullerenes manifest considerably higher reactivity toward the R1 radicals than fullerene C60 and methanofullerenes C60CX1X2 (X1 = X2 = CO2Et; X1 = CO2Me, X2 = OP(OMe)2, X1 = X2 = OP(OEt)2).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. G. Gasanov, V. V. Bashilov, B. L. Tumanskii, V. I. Sokolov, I. A. Nuretdinov, V. V. Zverev, V. P. Gubskaya, and L. Sh. Berezhnaya, Izv. Akad. Nauk, Ser. Khim., 2003, 364 [Russ. Chem. Bull., Int. Ed., 2003, 52, 380 (Engl. Transl.)].

  2. V. P. Gubskaya, N. P. Konovalova, I. A. Nuretdinov, G. M. Fazleeva, L. Sh. Berezhnaya, F. G. Sigbatullina, and I. P. Karaseva, Izv. Akad. Nauk, Ser. Khim., 2002, 1582 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1723].

  3. J. P. Perdew, K. Burke, and M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.

    Google Scholar 

  4. D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151.

    Google Scholar 

  5. D. N. Laikov, Abstrs. 2nd V. A. Fock All-Russian School (Conference) on Quantum and Computational Chemistry, Novgorod, 2000, 46.

  6. M. W. Schmidt, K. K. Baldridge, J. A. Boatz, S. T. Elbert, M. S. Goredon, J. H. Jensen, S. Koseki, N. Matsunada, K. A. Nguyen, S. J. Su, T. L. Windus, and J. A. Montgomery, J. Comput. Chem., 1993, 14, 1347.

    Google Scholar 

  7. R. G. Gasanov and R. Kh. Freidlina, Usp. Khim., 1987, 56, 447 [Russ. Chem. Rev., 1987, 56, 264 (Engl. Transl.)].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    R. G. Gasanov, B. L. Tumanskii & M. V. Tsikalova

  2. Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    I. A. Nuretdinov, V. P. Gubskaya, V. V. Zverev & G. M. Fazleeva

Authors
  1. R. G. Gasanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. L. Tumanskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Tsikalova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Nuretdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. P. Gubskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. V. Zverev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. G. M. Fazleeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gasanov, R.G., Tumanskii, B.L., Tsikalova, M.V. et al. Spin-adducts of radicals ·P(O)(OPri)2 and ·CMe3 with pyrrolidino[60]fullerenes studied by ESR spectroscopy. Russian Chemical Bulletin 52, 2675–2678 (2003). https://doi.org/10.1023/B:RUCB.0000019885.02675.38

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUCB.0000019885.02675.38

Search

Navigation