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Catalytic oxidation of aliphatic alcohols in the tetraaquapalladium(ii) complex—iron(iii)—dioxygen system

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Abstract

The selective low-temperature (40—70 °C) catalytic oxidation of methanol, propan-1-ol, and propan-2-ol in the presence of the tetraaquapalladium(ii) complex and iron(iii) ions and/or molecular oxygen as cooxidants was studied. The corresponding carbonyl compound is the product of alcohol oxidation. The kinetic regularities of the reaction were established. In the reaction mechanism proposed, the key step is palladium(i) formation.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, (Technical University), 26 Moskovskii prosp., 198013, St. Petersburg, Russian Federation

    V. V. Potekhin, S. N. Solov"eva & V. M. Potekhin

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  1. V. V. Potekhin
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  2. S. N. Solov"eva
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  3. V. M. Potekhin
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Potekhin, V.V., Solov"eva, S.N. & Potekhin, V.M. Catalytic oxidation of aliphatic alcohols in the tetraaquapalladium(ii) complex—iron(iii)—dioxygen system. Russian Chemical Bulletin 52, 2668–2674 (2003). https://doi.org/10.1023/B:RUCB.0000019884.21081.a0

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