Abstract
Complexation of crown ether vinylogs containing different terminal polar groups with alkali and alkali-earth metal ions in solutions was studied by spectrophotometry. The hypsochromic shift of absorption band maxima in the UV-Vis absorption spectra indicates that the ligands containing the monobenzocrown ether fragments interact with metal ions. The scheme of complexation was proposed, and the stability constants of the complexes were determined. The efficiency of complexation depends on the metal cation size and the structure of the ionophoric fragment.
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Strokach, Y.P., Valova, T.M., Barachevsky, V.A. et al. Influence of metal cations on spectral characteristics of crown ether vinylogs with different terminal polar groups. Russian Chemical Bulletin 52, 2656–2660 (2003). https://doi.org/10.1023/B:RUCB.0000019882.83237.01
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DOI: https://doi.org/10.1023/B:RUCB.0000019882.83237.01