Abstract
Amidate-bridged dinuclear PtIII complexes having a PtIII—PtIII bond react with ketones and alkenes. In the reaction with alkenes in water, 1,2-diols are obtained. In the reactions with conjugated dienes, stereospecific 1,4-diols are formed selectively. A kinetic study revealed that at each intermediate step of the reaction with alkenes the electronic state of the Pt—Pt bond changes between PtIII—PtIII and PtII—PtIV and stabilizes the reaction intermediates.
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Matsumoto, K. Inorganic and organometallic chemistry of PtIII complexes having a delocalized PtIII—PtIII bond. Russian Chemical Bulletin 52, 2577–2587 (2003). https://doi.org/10.1023/B:RUCB.0000019875.23279.fa
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DOI: https://doi.org/10.1023/B:RUCB.0000019875.23279.fa