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Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine

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Abstract

The reactions of the polymeric complex [Co(OH)n(OOCCMe3)2–n ]x (1) with 2-amino-5-methylpyridine (L1) and 2,6-diaminopyridine (L2) under anaerobic conditions at the ratio M : L = 1 : 1 afforded the binuclear complexes Co2(μ-OOCCMe3)4[η-MeC5H3N(NH2)]2 (2) and Co2(μ-OOCCMe3)4[η-C5H3N(NH2)2]2 (3), respectively, with Chinese-lantern-like structures. The reaction of the tetranuclear cobalt(ii) complex Co4(μ3-OH)2(μ-OOCCMe3)4(η2-OOCCMe3)2(EtOH)6 (4) with 2,6-diaminopyridine under anaerobic conditions at the ratio M : L2 = 2 : 1 gave rise to the antiferromagnetic tetranuclear complex Co4(μ4-O)[μ-C5H3N(NH2)2]2(μ-OOCCMe3)4(η2-OOCCMe3)2 (5) with tetradentate-bridging coordination of the oxygen atom. The structures of the compounds synthesized were established by X-ray diffraction analysis.

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References

  1. M. A. Porai-Koshits and A. S. Antsyshkina, Dokl. Akad. Nauk SSSR, 1962, 146, 1102 [Dokl. Chem., 1962 (Engl. Transl.)].

    Google Scholar 

  2. A. A. Pasynskii, T. Ch. Idrisov, K. M. Suvorova, V. M. Novotortsev, V. V. Zelentsov, and V. T. Kalinnikov, Dokl. Akad. Nauk SSSR, 1975, 220, 881 [Dokl. Chem., 1975 (Engl. Transl.)].

    Google Scholar 

  3. M. Morooka, S. Ohba, M. Nakashima, T. Tokaii, Y. Muto, M. Kato, and O. W. Steward, Acta Crystallogr., Sect. C, 1992, 48, 1888.

    Google Scholar 

  4. N. Hirashima, S. Nusebye, M. Kato, K. Maartmann-Moe, Y. Muto, M. Nakashima, and T. Tokaii, Acta Chem. Scand., Ser. A, 1990, 44, 984.

    Google Scholar 

  5. I. L. Eremenko, S. E. Nefedov, A. A. Sidorov, and I. I. Moiseev, Izv. Akad. Nauk, Ser. Khim., 1999, 409 [Russ. Chem. Bull., 1999, 48, 405 (Engl. Transl.)].

    Google Scholar 

  6. G. Smith, E. J. O´Reilly, and C. H. Kennard, Aust. J. Chem., 1983, 36, 2175.

    Google Scholar 

  7. J. Catterick, M. B. Hursthouse, P. Thornton, and A. J. Welch, J. Chem. Soc., Dalton Trans., 1977, 223.

  8. Y. Cui, F. Zheng, and J. Huang, Acta Crystallogr., Sect. C, 1999, 55, 1067.

    Google Scholar 

  9. T. Hokelek and H. Necefoglu, Acta Crystallogr., Sect. C, 1997, 53, 187.

    Google Scholar 

  10. I. L. Eremenko, S. E. Nefedov, A. A. Sidorov, M. A. Golubnichaya, P. V. Danilov, V. N. Ikorskii, Y. G. Shvedenkov, V. M. Novotortsev, and I. I. Moiseev, Inorg. Chem., 1999, 38, 3764.

    Google Scholar 

  11. M. A. Golubnichaya, A. A. Sidorov, I. G. Fomina, L. T. Eremenko, S. E. Nefedov, I. L. Eremenko, and I. I. Moiseev, Zh. Neorg. Khim., 1999, 44, 1479 [Russ. J. Inorg. Chem., 1999, 44, 1479 (Engl. Transl.)].

    Google Scholar 

  12. C.-C. Wang, W.-C. Lo, C.-C. Chou, G.-H. Lee, J.-M. Chen, and S.-M. Peng, Inorg. Chem., 1998, 37, 4059.

    Google Scholar 

  13. S.-Y. Lai, T.-W. Lin, Y.-H. Chen, C.-C. Wang, G.-H. Lee, M.-H. Yang, M.-K. Leung, and S.-M. Peng, J. Am. Chem. Soc., 1999, 121, 250.

    Google Scholar 

  14. M. A. Golubnichaya, A. A. Sidorov, I. G. Fomina, M. O. Ponina, S. M. Deomidov, S. E. Nefedov, I. L. Eremenko, and I. I. Moiseev, Izv. Akad. Nauk, Ser. Khim., 1999, 1773 [Russ. Chem. Bull., 1999, 48, 1751 (Engl. Transl.)].

    Google Scholar 

  15. SMART (Control) and SAINT (Integration) Software, Version 5.0, Bruker AXS Inc., Madison, WI, 1997.

  16. G. M. Sheldrick, SADABS, Program for Scanning and Correction of Area Detector Data, University of Göttingen, Göttingen (Germany), 1997.

    Google Scholar 

  17. G. M. Sheldrick, SHELX97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen (Germany), 1997.

    Google Scholar 

  18. G. M. Sheldrick, SHELXL97. Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany), 1997.

    Google Scholar 

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. V. Pakhmutova, A. E. Malkov, T. B. Mikhailova, A. A. Sidorov, I. G. Fomina, G. G. Aleksandrov, V. M. Novotortsev & I. L. Eremenko

  2. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    V. N. Ikorskii

Authors
  1. E. V. Pakhmutova
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  2. A. E. Malkov
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  3. T. B. Mikhailova
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  4. A. A. Sidorov
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  5. I. G. Fomina
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  6. G. G. Aleksandrov
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  7. V. M. Novotortsev
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  8. V. N. Ikorskii
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  9. I. L. Eremenko
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Pakhmutova, E.V., Malkov, A.E., Mikhailova, T.B. et al. Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine. Russian Chemical Bulletin 52, 2117–2124 (2003). https://doi.org/10.1023/B:RUCB.0000011866.57209.5b

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  • DOI: https://doi.org/10.1023/B:RUCB.0000011866.57209.5b

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