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On Assessment of the Thermodynamic Consistency of Data on Liquid-Vapor Equilibrium

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Abstract

A new method for assessment of the thermodynamic consistency of binary isothermal data on the liquid-vapor equilibrium by calculating the Redlich-Kiester integral with account of how the pressure of phase coexistence depends on the vapor composition is suggested. The Maple 8 software is used to compare the values of the integral, other characteristics calculated for systems with varied nature of departures from the Raoult law.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    A. N. Marinichev

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  1. A. N. Marinichev
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Marinichev, A.N. On Assessment of the Thermodynamic Consistency of Data on Liquid-Vapor Equilibrium. Russian Journal of Applied Chemistry 77, 891–895 (2004). https://doi.org/10.1023/B:RJAC.0000044111.83007.77

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  • DOI: https://doi.org/10.1023/B:RJAC.0000044111.83007.77

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