Abstract
The extraction of molybdenum(VI) from aqueous-peroxide solutions of sodium tungstate with a trialkylamine-isooctyl alcohol mixture in kerosene was studied in relation to the ratio of the organic and aqueous phases, hydrogen peroxide and hydrogen chloride consumption, and the ratio of molybdenum(VI) and tungsten (VI) in the aqueous phase. A method for additional purification of the raffinate to remove molybdenum was developed.
Similar content being viewed by others
REFERENCES
Zelikman, A.N., Metallurgiya tugoplavkikh redkikh metallov (Metallurgy of Rare Refractive Metals), Moscow: Metallurgiya, 1986.
Vol’dman, G.M., Zelikman, A.N., Ziberov, G.N., et al., Dokl. Akad. Nauk SSSR, 1977, vol. 232, no. 3, pp. 660–662.
Vol’dman, G.M., Zelikman, A.N., Ziberov, G.N., and Kagerman’yan, V.S., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1978, no. 3, pp. 46–49.
Blokhin, A.A., Pak, V.I., Pirmatov, E.A., et al., Tsvetn. Met., 1994, no. 8, pp. 41–42.
US Patent 4278642.
US Patent 4288413.
Giganov, G.P., Tserekova, A.M., Agnokov, T.Sh., et al., Tsvetn. Met., 1988, no. 5, pp. 67–71.
Vol’dman, G.M. and Zelikman, A.N., Zh. Neorg. Khim., 1993, vol. 38, no. 7, pp. 1234–1245.
Voropanova, L.A. and Barvinyuk, N.G., Tsvetn. Metall., 2002, nos. 4-5, pp. 21–25.
RF Patent 2186865.
Zelikman, A.N., and Kalinina, I.G., Zh. Neorg. Khim., 1974, vol. 19, no. 4, pp. 1040–1045.
RF Patent 2196862.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Voropanova, L.A., Barvinyuk, N.G. Extraction of Molybdenum(VI) from Aqueous-Peroxide Solutions of Sodium Tungstate with Trialkylamine. Russian Journal of Applied Chemistry 77, 759–762 (2004). https://doi.org/10.1023/B:RJAC.0000038807.41664.f4
Issue Date:
DOI: https://doi.org/10.1023/B:RJAC.0000038807.41664.f4