Abstract
Phase diagrams of ternary liquid systems constituted by tetadecane (hexane, decane), tri-n-butyl phophate, and cerium(III) nitrate solvate with tri-n-butyl phosphate Ce(NO3)3(TBP)3 with phase separation into liquid phases I and II were studied at 298.15 K. Phase I is enriched in the hydrocarbon diluent, and phase II, in Ce(NO3)3(TBP)3. The distribution of components between phases I and II was considered.
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REFERENCES
Pyartman, A.K., Kopyrin, A.A., Puzikov, E.A., and Bogatov, K.B., Radiokhimiya, 1995, vol. 37, no. 1, pp. 52–55.
Nikolotova, Z.I., Ekstraktsiya neitral'nymi fosfororganicheskimi soedineniyami: Aktinoidy: Spravochnik (Extraction with Neutral Organophophorus Compounds: Actinides, Handbook), Moscow: Energoatomizdat, 1987.
Ekstraktsiya neorganicheskikh veshchestv (Diagrammy rassloeniya, raspredeleniya, vysalivaniya i razdeleniya) (Extraction of Inorganic Substances (Diagrams of Phase Separation, Distribution, Salting-Out, and Separation)), Nikolaev, A.V., Ed., Novosibirsk: Nauka, 1970.
Pribil, R., Analytical Applications of EDTA and Related Compounds, Oxford: Pergamon, 1972.
Treybal, R.E., Liquid Extraction, New York: McGraw-Hill, 1963.
Mikhailov, V.A., Kharchenko, S.K., and Nazin, A.G., Izv. Sib. Otd. Akad. Nauk SSSR, 1961, no. 7, pp. 50–56.
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Pyartman, A.K., Kudrova, A.V. & Keskinov, V.A. Phase Separation in the Systems Constituted by Tetradecane (Hexane, Decane), Tri-n-Butyl Phosphate, and Cerium(III) Nitrate Solvate with Tri-n-Butyl Phosphate. Russian Journal of Applied Chemistry 77, 555–558 (2004). https://doi.org/10.1023/B:RJAC.0000038665.87511.03
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DOI: https://doi.org/10.1023/B:RJAC.0000038665.87511.03