Abstract
Molybdenum oxide groups were synthesized on a porous glass surface by the molecular layering technique. Kinetic features of Mo(V) ⇄ Mo(VI) transitions in thermal oxidation and photoreduction were studied for a set of samples containing 0.02-0.12 mmol g- 1 of molybdenum.
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REFERENCES
Gavrilyuk, A.I. and Sekushin, N.A., Elektrokhromizm i fotokhromizm v oksidakh vol'frama i molibdena (Electrochromism and Photochromism in Tungsten and Molybdenum Oxides), Leningrad: Nauka, 1990.
Andreev, V.N., Nikitin, S.E., Klimov, V.A., et al., Fiz. Tverd. Tela, 2001, vol. 43, no. 4, pp. 755–758.
He, T., Ma, Y., Cao, Y.A., Jang P., et al., Langmuire, 2001, vol. 17, no. 26, pp. 8024–8027.
Quevedo-Lopez, M.A., Ramirez-Bon, R., Orozko-Teran, R.A., et al., Thin Solid Films, 1999, vols. 343-344, no. 1, pp. 202–205.
Scarminio, J., Lourenco, A., and Gorenstein, A., Thin Solid Films, 1997, vol. 302, nos. 1-2, pp. 66–70.
Aleskovskii, V.B., Khimiya tverdykh veshchestv (Chemistry of Solid Substances), Moscow: Vysshaya Shkola, 1978.
Pak, V.N., Vorob'eva, G.G., and Ragulin, G.K., Zh. Fiz. Khim., 1986, vol. 60, no. 1, pp. 251–253.
Olifirenko, V.V., Davydov, A.A., and Pak, V.N., Zh. Prikl. Khim., 1990, vol. 63, no. 11, pp. 2505–2509.
Pak, V.N. and Vorob'eva, G.G., Zh. Prikl. Khim., 1988, vol. 61, no. 10, pp. 2212–2215.
Eksperimental'nye metody v adsorbtzii i katalize (Experimental Techniques in Adsorption and Catalysis), Nikitin, Yu.S., Ed., Moscow: Mos. Gos. Univ, 1990.
Analiz mineral'nogo syr'ya (Analysis of Mineral Raw Materials), Knipovich, Yu.N. and Morachevskii, Yu.V., Eds., Leningrad: Khimiya, 1956, pp. 804–810.
Kiselev, A.V. and Lygin, V.I., Infrakrasnye spektry poverkhnostnykh soedinenii (IR Spectra of Surface Compounds), Moscow: Nauka, 1972.
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Pak, V.N., Potkina, G.G., Sukhanov, S.V. et al. Thermal Oxidation and Photochromic Properties of Molybdenum-containing Porous Glasses Obtained by Molecular Layering. Russian Journal of Applied Chemistry 77, 538–542 (2004). https://doi.org/10.1023/B:RJAC.0000038662.29172.89
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DOI: https://doi.org/10.1023/B:RJAC.0000038662.29172.89