Skip to main content

Use of Cobalt(II) Phthalocyanine Sulfonates in Gas Purification To Remove Hydrogen Sulfide

Russian Journal of Applied Chemistry volume 76, pages 1946–1950 (2003)Cite this article

Abstract

Experiments on liquid-phase oxidation of H2S with oxygen in the presence of catalysts, cobalt phthalocyanine sulfonates CoPc(SO3Na) n , were performed on a laboratory static installation in order to find conditions under which a stationary oxidation mode can be established at pH ≥ 8. The influence exerted by additional introduction of a soluble salt of Mn2 + (MnSO4, MnCl2) into the reaction mixture at various pH values was studied.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. Kundo, N.N. and Keier, N.P., Kinet. Kataliz, 1970, vol. 11, no. 1, pp. 91–99.

    Google Scholar 

  2. Simonov, A.D., Keier, N.P., Kundo, N.N., et al., Kinet. Kataliz, 1973, vol. 14, no. 4, pp. 988–992.

    Google Scholar 

  3. Stuchinskaya, T.L., Maizlish, V.E, Kundo, N.N., and Smirnov, R.P., Zh. Prikl. Khim., 1993, vol. 66, no. 5, pp. 1039–1043.

    Google Scholar 

  4. Abel, E.W., Chem. Commun., 1971, no. 9, pp. 449–450.

    Google Scholar 

  5. Wagnerova, D.M., Schwertnerova, E., and VepřekŠišska, J., Coll. Czech. Chem. Commun., 1974, vol. 39, no. 8, pp. 1980–1988.

    Google Scholar 

  6. Faddeenkova, G.A. and Kundo, N.N., Zh. Prikl. Khim., 1979, vol. 52, no. 10, pp. 2161–2165.

    Google Scholar 

  7. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

    Google Scholar 

  8. TU (Technical Specification) 2061-49, Lead Indicator Paper.

  9. Lazarev, V.I. and Kostrikov, V.I., Zh. Anal. Khim., 1970, vol. 25, no. 3, pp. 553–555.

    Google Scholar 

  10. Kreshkov, A.P., Osnovy analiticheskoi khimii (Fundamentals of Analytical Chemistry), Moscow: Khimiya, 1976, vol. 1, 4th ed.

    Google Scholar 

  11. Kreshkov, A.P., Osnovy analiticheskoi khimii (Fundamentals of Analytical Chemistry), Moscow: Khimiya, 1970, vol. 2, 3rd ed.

    Google Scholar 

  12. Vasilevskaya, L.S. and Golyand, S.M., Zh. Prikl. Khim., 1978, vol. 51, no. 8, pp. 1887–1889.

    Google Scholar 

  13. Rybakov, L.A., Afanas'ev, Yu.M., Shimko, I.G., and Chinennaya, S.K., Khim. Volokna, 1984, no. 6, pp. 12–14.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    G. A. Faddeenkova & N. N. Kundo

Authors
  1. G. A. Faddeenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Kundo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Faddeenkova, G.A., Kundo, N.N. Use of Cobalt(II) Phthalocyanine Sulfonates in Gas Purification To Remove Hydrogen Sulfide. Russian Journal of Applied Chemistry 76, 1946–1950 (2003). https://doi.org/10.1023/B:RJAC.0000022444.05065.00

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RJAC.0000022444.05065.00

Keywords

  • Oxidation
  • Hydrogen
  • Sulfide
  • Cobalt
  • Stationary Oxidation