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Dipole Structure and Electrooptical Properties of Poly-N-vinylpyrrolydone in Nonaqueous Solvents

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Abstract

Electrooptical Kerr effect and dielectric polarization were studied for poly-N-vinylpyrrolidone solutions in chloroform and in mixed chloroform-CCl4 solvent. The results were compared with those for an analogue of the monomeric unit of poly-N-vinylpyrrolidone, low-molecular-weight compound N-methylpyrrolidone.

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References

  1. Kirsh, Yu. E., Poli-N-vinilpirrolidon i drugie poli-Nvinilamidy: Sintez i fiziko-khimicheskie svoistva (Poly-N-Vinylpirrolidone and Other Poly-N-Vinylamides: Synthesis and Physicochemical Properties), Moscow: Nauka, 1998.

    Google Scholar 

  2. Evlampieva, N.P., Lavrenko, P.N., Melenevskaya E.Yu., et al., Fiz. Tverd. Tela, 2002, vol. 44, issue 3, pp. 537–540.

    Google Scholar 

  3. Ryumtsev, E.I., Evlampieva, N.P., Nazarova, O.V., et al., Dokl. Ross. Akad. Nauk, 2003 (in press).

  4. Frisman, E.V. and Sibileva, M.A., Vysokomol. Soedin., 1961, vol. 3, no. 7, pp. 1284–1287.

    Google Scholar 

  5. Tsvetkov, V.N., Zhestkotsepnye polimernye molekuly (Rigid-Chain Polymer Molecules), Leningrad: Nauka, 1986.

    Google Scholar 

  6. Evlampieva, N.P., Yakimanskii, A.V., Pavlov, G.M., et al., Zh. Prikl. Khim., 2002, vol. 75, no. 10, pp. 1699–1706.

    Google Scholar 

  7. Minkin, V.I., Osipov, O,A., and Zhdanov, Yu.A., Dipol'nye momenty v organicheskoi khimii (Dipole Moments in Organic Chemistry), Leningrad: Khimiya, 1968.

    Google Scholar 

  8. Zhidkokristallicheskii poryadok v polimerakh (Liquid Crystalline Order in Polymers), Blyumshtein, A., Ed. Moscow: Mir, 1981, issue 2.

    Google Scholar 

  9. Tsvetkov, V.N., Rjumtsev, E.I., Shtennikov, I.N., et al., Eur. Polym. J., 1973, vol. 9, pp. 481–492.

    Google Scholar 

  10. Tsvetkov, V.N., Eskin, V.E., and Frenkel, S.Ya., Struktura makromolekul v rastvorakh (Structure of Macromolecules in Solutions), Moscow: Nauka, 1965.

    Google Scholar 

  11. Flory, P.J., Statistical Mechanics of Chain Molecules, New York: Interscience, 1969.

    Google Scholar 

  12. Pavlov, G.M., Panarin, E.F., Korneeva, E.V., et al., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 6, pp. 1190–1196.

    Google Scholar 

  13. Stewart, J.J.P., J. Comput. Chem., 1989, vol. 10, pp. 209–220.

    Google Scholar 

  14. Stewart, J.J.P., Orbital Program, J. Computer-Aided Mol. Des., 1990, no. 4, pp. 1–105.

    Google Scholar 

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Evlampieva, N.P., Dmitrieva, T.A. & Ryumtsev, E.I. Dipole Structure and Electrooptical Properties of Poly-N-vinylpyrrolydone in Nonaqueous Solvents. Russian Journal of Applied Chemistry 76, 1637–1642 (2003). https://doi.org/10.1023/B:RJAC.0000015728.02928.c0

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  • DOI: https://doi.org/10.1023/B:RJAC.0000015728.02928.c0

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