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Phase Relations and Electrical Properties of Phases in Systems Na2MoO4-AMoO4-R2(MoO4)3 (A = Mg, Mn, Co, Ni; R = Cr, Fe)

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Abstract

The subsolidus region of ternary salt systems Na2MoO4-AMoO4-R2(MoO4)3 was studied. It was established that phases Na1-x A1-x R1+x (MoO4)3, 0 ≤ x ≤ 0.2-0.3 of variable composition with rhombohedral lattice (R-3c) and ternary molybdates NaA3R(MoO4)5 of triclinic crystal system (P-1) are formed in the system. The electrical characteristics of ternary molybdates and the effect of the cation nature on the homogeneity region of the phases and type of conduction were studied.

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  1. Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Ulan-Ude, Buryatia, Russia

    I. Yu. Kotova & N. M. Kozhevnikova

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  1. I. Yu. Kotova
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  2. N. M. Kozhevnikova
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Kotova, I.Y., Kozhevnikova, N.M. Phase Relations and Electrical Properties of Phases in Systems Na2MoO4-AMoO4-R2(MoO4)3 (A = Mg, Mn, Co, Ni; R = Cr, Fe). Russian Journal of Applied Chemistry 76, 1572–1576 (2003). https://doi.org/10.1023/B:RJAC.0000015715.82902.e0

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  • DOI: https://doi.org/10.1023/B:RJAC.0000015715.82902.e0

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