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Kinetic evidence for the mechanism of liquid-solid phase oxidation of alcohols

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Abstract

Benzyl alcohol oxidation is catalyzed by solid MnFe1.8Cu0.15Ru0.05O4 in the presence of molecular oxygen. The good compliance of oxidation kinetics with the Michaelis-Menten enzyme kinetic model evidences the oxidative dehydrogenation of benzyl alcohol via a Ru-alkoxide intermediate, which undergoes b-elimination to afford benzaldehyde.

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Authors and Affiliations

  1. School of Chemical Engineering, South China University of Technology, Guangzhou, 510640, P.R.China

    Hong-Bing Ji, Jun Song, Beisi He & Yu Qian

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  1. Hong-Bing Ji
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  2. Jun Song
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  3. Beisi He
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  4. Yu Qian
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Correspondence to Hong-Bing Ji.

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Ji, HB., Song, J., He, B. et al. Kinetic evidence for the mechanism of liquid-solid phase oxidation of alcohols. Reaction Kinetics and Catalysis Letters 82, 97–103 (2004). https://doi.org/10.1023/B:REAC.0000028810.01091.80

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  • DOI: https://doi.org/10.1023/B:REAC.0000028810.01091.80

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