Skip to main content
SpringerLink
Log in

Thermal stability of wüstite structure modified with calcium cations

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Wüstite modified with calcium cations was prepared by high temperature fusion. Mössbauer spectroscopy and X-ray diffraction were employed to identify wüstite phases before and after thermal treatment at elevated temperatures in vacuum with a base pressure of 1.33 Pa for 60 h. Experimental results demonstrated that the location of calcium cations inside the wüstite structure could prevent disproportionation into magnetite and α-iron.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. R.M. Hazen, R. Jeanloz: Rev. Geophys. Space Phys., 22, 37 (1984).

    CAS  Google Scholar 

  2. L.S. Darken, R.W. Gurry: J. Am. Chem. Soc., 67, 1398 (1945).

    CAS  Google Scholar 

  3. L.S. Darken, R.W. Gurry: J. Am. Chem. Soc., 68, 798 (1946).

    Article  CAS  Google Scholar 

  4. S. Stolen, R. Glockner, F. Gronvold: Thermochim. Acta., 256, 91 (1995).

    Article  CAS  Google Scholar 

  5. D.I. Ryzonkov, S.B. Sorin: Solid State Ionics, 117, 145 (1999).

    Article  Google Scholar 

  6. T. Kodama, K. Tominaga, M. Tabata, T. Yoshida, Y. Tamaura: J. Am. Ceram. Soc., 75, 1287 (1992).

    Article  CAS  Google Scholar 

  7. C.L. Zhang, S. Li, T.H. Wu, S.Y. Peng: Mater. Chem. Phys., 58, 139 (1999).

    Article  CAS  Google Scholar 

  8. A. Pattek-Janczyk, J.C. Grenier, B. Miczko: Solid State Ionics, 117, 95 (1999).

    Article  CAS  Google Scholar 

  9. H.Z. Liu, R.Y. Xu, Z.R. Jiang, Z.N. Hu, Y.Y. Li, X.N. Li: Fe 1-x O-based catalyst for ammonia synthesis, U.S. Pat., 5846507 (1998).

  10. T. Sano, M. Tsuji, Y. Tamaura: Solid State Ionics, 104, 311 (1997).

    Article  CAS  Google Scholar 

  11. A. Tazi, R. Gerardin, F.J.O. Evrard: Mat. Res. Bull., 30, 829 (1995).

    Article  CAS  Google Scholar 

  12. C. McCammon: Science, 259, 66 (1993).

    CAS  Google Scholar 

  13. N.N. Greenwood, T.C. Gibb: Mössbauer Spectroscopy, p. 249. Chapman and Hall, London 1971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Zhejiang University of Technology, Zhejiang Key Laboratory of Heterogeneous Catalysis, Hangzhou, 310014, P.R. China

    Xiaonian Li, Yaqing Cen & Huazhang Liu

  2. Department of Physics, Shuzhou University, Shuzhou, 215006, P.R. China

    Yusheng Xu

  3. Analysis Center, Zhejiang University, Hangzhou, 310012, P.R. China

    Guanglie Lv

Authors
  1. Xiaonian Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yaqing Cen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Huazhang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yusheng Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Guanglie Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xiaonian Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, X., Cen, Y., Liu, H. et al. Thermal stability of wüstite structure modified with calcium cations. Reaction Kinetics and Catalysis Letters 81, 313–320 (2004). https://doi.org/10.1023/B:REAC.0000019438.14134.3c

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:REAC.0000019438.14134.3c

Search

Navigation