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Kinetic investigations on interaction of carbon monoxide with RuIICl2(PPh3)3 in mixed aqueous medium

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Abstract

Kinetics, equilibrium and thermodynamics of interaction of CO with RuCl2(PPh3)3 (1) have been investigated in 1:1(v/v) water — 1,4-dioxan mixture in which 1 dissociates to RuCl2(PPh3)2 (1a), by losing a coordinated PPh3. The kinetics of complexation of (1a) with CO to form RuCl2(CO)(PPh3)2 (2) indicated first order dependence in [1a] and [CO]. The thermodynamic parameters for the formation of 2 were determined.

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Authors and Affiliations

  1. Silicates and Catalysis Division, Central Salt and Marine Chemicals Research Institute, Bhavnagar, 364002, India

    Vivek K. Srivastava, Ram S. Shukla, Sharad D. Bhatt & Raksh V. Jasra

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  1. Vivek K. Srivastava
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  2. Ram S. Shukla
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  3. Sharad D. Bhatt
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  4. Raksh V. Jasra
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Correspondence to Ram S. Shukla.

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Srivastava, V.K., Shukla, R.S., Bhatt, S.D. et al. Kinetic investigations on interaction of carbon monoxide with RuIICl2(PPh3)3 in mixed aqueous medium. Reaction Kinetics and Catalysis Letters 81, 99–105 (2004). https://doi.org/10.1023/B:REAC.0000016522.47890.a8

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  • DOI: https://doi.org/10.1023/B:REAC.0000016522.47890.a8

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