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Selective oxidation of octadecan-1-ol to octadecanoic acid over Co3O4/SiO2 catalysts

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Abstract

Factors (reaction temperature, reaction time, flow rate of oxygen, amount of catalyst, etc.) influencing the catalytic properties of Co3O4/SiO2catalyst in the oxidation octadecan-1-ol to octadecanoic acid were investigated. The catalysts were characterized by means of XRD, FT-IR and N2-adsorption. The experimental results indicate that under the optimal condition the selectivity to octadecanoic acid reached 97.5 % over 5 % Co3O4/SiO2 catalyst.

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Authors and Affiliations

  1. College of Chemistry, Jilin University, ChangChun, 130023, P. R. China

    Zhuang Hong, Cheng Tiexin, Bi Yingli, Zhou Guangdong & Zhen Kaiji

Authors
  1. Zhuang Hong
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  2. Cheng Tiexin
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  3. Bi Yingli
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  4. Zhou Guangdong
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  5. Zhen Kaiji
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Correspondence to Bi Yingli.

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Hong, Z., Tiexin, C., Yingli, B. et al. Selective oxidation of octadecan-1-ol to octadecanoic acid over Co3O4/SiO2 catalysts. Reaction Kinetics and Catalysis Letters 81, 13–20 (2004). https://doi.org/10.1023/B:REAC.0000016511.39679.9e

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  • DOI: https://doi.org/10.1023/B:REAC.0000016511.39679.9e

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