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Catalytic hydrogenation by recyclable supported Pd(II)-amino acid complex

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Abstract

L-phenyl alanine was anchored to P(S-DVB) resin and its complex with PdCl2 was prepared. The newly synthesized catalyst was found to be a versatile and recyclable catalyst for the hydrogenation of 1-octene and acetophenone. This chiral catalyst induced moderate enantioselectivity during the asymmetric reduction of acetophenone.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, M.S.University of Baroda, Vadodara, 390 002, India

    Vaibhav B. Valodkar, Rajnath Ram & Hoskote S. Rama

  2. Research Centre, Indian Petrochemicals Corporation Limited, Vadodara, 391 346, India

    Gopal L. Tembe & Marayil Ravindranathan

Authors
  1. Vaibhav B. Valodkar
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  2. Gopal L. Tembe
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  3. Marayil Ravindranathan
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  4. Rajnath Ram
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  5. Hoskote S. Rama
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Correspondence to Gopal L. Tembe.

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Valodkar, V.B., Tembe, G.L., Ravindranathan, M. et al. Catalytic hydrogenation by recyclable supported Pd(II)-amino acid complex. Reaction Kinetics and Catalysis Letters 80, 285–291 (2003). https://doi.org/10.1023/B:REAC.0000006137.78049.41

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  • DOI: https://doi.org/10.1023/B:REAC.0000006137.78049.41

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