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Aromatic polycarbonates by direct synthesis from bisphenol a and carbon monoxide

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Abstract

Oxidative carbonylation of bisphenol A to polycarbonates has been studied using mixtures of carbon monoxide and oxygen in the presence of a host of catalytic systems. Catalysts containing palladium compounds and selenium, as well as PdCl2/Fe/I2 and Pd/Fe/I2 catalytic systems, exhibit different selectivity and activity towards the products obtained.

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Authors and Affiliations

  1. Department of Chemistry, The University of Warsaw, 02-093, Warsaw, Pasteura 1, Poland

    Jadwiga Skupińska

  2. Industrial Chemistry Research Institute, 01-793, Warsaw, Rydygiera 8, Poland

    Longina Kuczyńska & Zbigniew Wielgosz

Authors
  1. Jadwiga Skupińska
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  2. Longina Kuczyńska
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  3. Zbigniew Wielgosz
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Skupińska, J., Kuczyńska, L. & Wielgosz, Z. Aromatic polycarbonates by direct synthesis from bisphenol a and carbon monoxide. Reaction Kinetics and Catalysis Letters 80, 269–276 (2003). https://doi.org/10.1023/B:REAC.0000006135.24753.f2

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  • DOI: https://doi.org/10.1023/B:REAC.0000006135.24753.f2

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