Skip to main content
Log in

Kinetics of propylene dimerization in the presence of a phosphite-modified, nickel based catalytic system

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Propylene dimerization by a catalytic system consisting of nickel(II)acetylacetonate, triphenylphosphite and diethylaluminium chloride has been studied. A kinetic analysis shows a first order dependence on catalyst and a second order dependence on propylene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. W. Keim: Angew. Chem. Int. Ed. Engl., 29, 235 (1990).

    Article  Google Scholar 

  2. Y. Chauvin, H. Olivier: Applied Homogeneous Catalysis with Organometallic Compounds,Vol.1, p. 258–268, VCH, New York 1996.

    Google Scholar 

  3. J. Skupinska: Chem. Rev., 91, 613 (1991).

    Article  CAS  Google Scholar 

  4. US 5 633 418 (1997).

  5. US 20010051758 (2001).

  6. B. Bogdanovich: Adv. Organomet. Chem., 17, 105 (1979).

    Google Scholar 

  7. P. Commereuc, Y. Chauvin, G. Leger, I. Gailard: Rev. Inst. Fr. Petr., 37, 639 (1982).

    CAS  Google Scholar 

  8. M. Mitkova, K. Kurtev: Izv. Vuzov, Khim. Khim. Tekh., 35, 27 (1992).

    CAS  Google Scholar 

  9. O.T. Onsager, H. Wang, V. Blindheim: Helv. Chim. Acta, 52, 197 (1969).

    Google Scholar 

  10. Y. Sakakobara, K. Alba, M. Sakai, N. Uchino: Bull. Inst. Chem. Res. Kyoto Univ., 57, 240 (1979).

    Google Scholar 

  11. M. Mitkova, A. Tomov, K. Kurtev: J. Mol. Cat. A: Chemical,110, 25 (1996).

    Article  CAS  Google Scholar 

  12. B. Bogdanovich: Adv. Organomet. Chem., 17, 105 (1979).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mitkova, M., Balbolov, E. Kinetics of propylene dimerization in the presence of a phosphite-modified, nickel based catalytic system. Reaction Kinetics and Catalysis Letters 80, 249–254 (2003). https://doi.org/10.1023/B:REAC.0000006132.55865.65

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:REAC.0000006132.55865.65

Navigation