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Partial Reactions of Copper Dissolution under Cathodic Polarization in Acidic Media

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Abstract

Experimental data on the copper dissolution under cathodic polarization (anomalous dissolution) are discussed. It is shown that anomalous copper dissolution is a complex process with mixed kinetics. The oxygen transport to the electrode surface is the main controlling stage. Stages of the copper oxidation and surface copper oxide dissolution account for a considerably smaller fraction of control. A simplified scheme of partial reactions on copper under its cathodic polarization is suggested.

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Authors and Affiliations

  1. Voronezh State University, Universitetskaya pl. 1, Voronezh, 394006, Russia

    I. V. Kreizer, I. K. Marshakov, N. M. Tutukina & I. D. Zartsyn

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  1. I. V. Kreizer
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  2. I. K. Marshakov
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  3. N. M. Tutukina
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  4. I. D. Zartsyn
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Kreizer, I.V., Marshakov, I.K., Tutukina, N.M. et al. Partial Reactions of Copper Dissolution under Cathodic Polarization in Acidic Media. Protection of Metals 40, 23–25 (2004). https://doi.org/10.1023/B:PROM.0000013107.65745.b0

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  • DOI: https://doi.org/10.1023/B:PROM.0000013107.65745.b0

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