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Simplified Topographic Model of Metal Dissolution: Comparison of Metals with Ideal and Real Lattices

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Abstract

A system of equations is formulated and solved for the dissolution model of a defect-free crystal with a simple cubic packing, which describes self-consistence of the atomic structure of a dissolving surface (including the edge concentration) and the dissolution rate. The enhanced corrosion resistance is shown to be associated with a small (edge concentration compared with that typical of a real defective crystal.

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Authors and Affiliations

  1. Institute of High Temperatures, Russian Academy of Sciences, Moscow, Russia

    G. Yu. Alekseev

  2. FGUP Karpov Institute of Physical Chemistry, ul. Vorontsovo Pole 10, Moscow, 103064, Russia

    Yu. V. Alekseev

Authors
  1. G. Yu. Alekseev
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  2. Yu. V. Alekseev
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  3. V. A. Bityurin
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Alekseev, G.Y., Alekseev, Y.V. & Bityurin, V.A. Simplified Topographic Model of Metal Dissolution: Comparison of Metals with Ideal and Real Lattices. Protection of Metals 39, 521–536 (2003). https://doi.org/10.1023/B:PROM.0000007845.83069.7b

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  • DOI: https://doi.org/10.1023/B:PROM.0000007845.83069.7b

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