Abstract
Appealing to the modern discussions, some problems of applying the Lippman and Gibbs equations to the adsorption on solid electrodes are considered. The possibility of using nonthermodynamic approaches for solving certain thermodynamic problems (particularly, the role of elastic and plastic deformations of the electrode surfaces in the adsorption processes, the orientation of surface bonds during the adsorption of anions, and others) is discussed. The coefficient of partial charge transfer and the electrosorption valence of anions on metals, as well as the role of electron tunneling in the formation of a contact electric resistance (CER) signal are considered. The relation between the charge transfer during the adsorption of an anion and the adsorption of the solvent and the surface restructuring of monocrystal electrodes is analyzed. The results are compared to the available literature data.
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Marichev, V.A. Methodological Aspects of the Partial Charge Transfer in the Adsorption of Anions. Part I. Protection of Metals 39, 505–520 (2003). https://doi.org/10.1023/B:PROM.0000007844.28605.24
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DOI: https://doi.org/10.1023/B:PROM.0000007844.28605.24