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Oxidation Behavior of a Re-Base Diffusion-Barrier/β-NiAl Coating on Nb–5Mo–15W at High Temperatures

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Abstract

A β-NiAl coating with or without a Re-base alloy layer was formed on a Nb–5Mo–15W alloy. The coated alloys were oxidized isothermally in air at 1373 and 1473 K. Electroplating of a high (more than 70at.%)-Re–Ni film, Cr-pack cementation, Ni plating, and then Al-pack cementation, in this sequence, formed a coating structure with Re-base alloy and β-NiAl layers. The Re-base alloy layers were comprised of an outer σ-phase in the Re–Cr(Ni) system and an inner χ-phase in the Re–Nb(Cr) system. It was found that reaction between the β-NiAl and the alloy substrate was significantly suppressed when the Re-base alloy layers were present. The Re-base σ and χ phases were found to be good candidates for a diffusion barrier against inward-Al diffusion because they have very low solubilities for Al.

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Author notes

  1. M. Fukumoto

    Present address: Akita University, Tegatagakuen-cho 1-1, Akita City, 010-8502, Japan

  2. A. Kasama

    Present address: Kurume Technical College, Kurume City, Saga Prefecture, Japan

Authors and Affiliations

  1. Research Group of Interface Control Engineering, Graduate School of Engineering, Hokkaido University, Kita-13 Nishi-8, Kita-Ku, Sapporo, 060-8628, Japan

    Y. Matsumura, M. Fukumoto, S. Hayashi & T. Narita

  2. Akita University, Tegatagakuen-cho 1-1, Akita City, 010-8502, Japan

    A. Kasama, I. Iwanaga & R. Tanaka

Authors
  1. Y. Matsumura
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  2. M. Fukumoto
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  3. S. Hayashi
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  4. A. Kasama
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  5. I. Iwanaga
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  6. R. Tanaka
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  7. T. Narita
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Correspondence to T. Narita.

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Matsumura, Y., Fukumoto, M., Hayashi, S. et al. Oxidation Behavior of a Re-Base Diffusion-Barrier/β-NiAl Coating on Nb–5Mo–15W at High Temperatures. Oxidation of Metals 61, 105–124 (2004). https://doi.org/10.1023/B:OXID.0000016279.88052.d9

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  • DOI: https://doi.org/10.1023/B:OXID.0000016279.88052.d9

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