Abstract
The individual and joint effects of alloying with copper, silicon, and molybdenum as well as titanium and niobium on the electrochemical corrosion and mechanical properties of chromium-nickel steel are investigated. It is shown that under the conditions of some corrosive media the chromium-nickel-molybdenum steel can be replaced by a steel additionally alloyed with silicon and copper and stabilized by titanium. The favorable role of copper, silicon, titanium, and niobium in the provision of high electrochemical corrosion and mechanical properties of the steel is discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Ya.M. Kolotyrkin, A. V. Plaskeev, V.M. Knyazheva, et al., “On the mechanism of molybdenum influence on the corrosion behavior of stainless steels,” Dokl. Akad. Nauk SSR, 243(6), 1483–1486 (1978).
A. V. Plaskeev, V. M. Knyazheva, Ya. M. Kolotyrkin, and V. B. Kozhevnikov, “Crystallochemical mechanism of the influence of low alloying additives on the process of dissolution of corrosion-resistant steels in active condition,” Zashchita Met., 17(6), 661–669 (1981).
N. D. Tomashev and G. P. Chernov, in: The Theory of Corrosion and Corrosion-Resistant Structural Alloys [in Russian], Metallurgiya, Moscow (1986).
V. M. Latimer, Oxidizing States of Elements and Their Potentials in Aqueous Media [Russian translation], Inostr. Literatura, Moscow (1954).
E. A. Lizlovs, “Effect of Mo, Cu, and P on anodic behavior of 17Cr steels,” Corrosion, 22(11), 297–308 (1966).
E. T. Shapovalov and M. Yu. Ustimenko, “Effect of the content of nickel, copper, and molybdenum on the corrosion resistance of alloy Kh20N40 in acid solutions,” Zashchita Met., 30(6), 570–574 (1994).
A. V. Plaskeev and V. M. Knyazheva, “Role of chromium in passivation processes of an iron-base alloy,” Zashchita Met., 30(6), 565–570 (1994).
S. A. Glazkova, G. L. Shvartz, L. I. Freiman, and F. N. Tavadze, “A study of the resistance of chromium-nickel steels alloyed with molybdenum and silicon to local corrosion,” Zashchita Met., 10(1), 9–16 (1974).
Ya.M. Kolotyrkin and V. M. Knazheva, “Investigation of the selective dissolution of steels and alloys by ?-spectrometry,” Scand. J. of Metallurgy, No. 7, 170–175 (1978).
É. G. Fel'dgandler and L. Ya. Savkina, “Effect of alloying on the susceptibility of steel 000Kh16N15M3 to intercrystalline corrosion,” Metalloved. Term. Obrab. Met., No. 11, 10–13 (1968).
L. P. Lozovatskaya, I. A. Levin, I. K. Burtseva, et al., “Increasing the resistance of steel 03Kh18N11 to ICC by correcting its chemical composition,” Zashchita Met., 20(3), 411–415 (1984).
E. F. Petrova and L. A. Shvartsman, “Effect of molybdenum on the thermodynamic activity of ?-iron,” in: Problems of Metal Science and Metal Physics, Coll. Works, No. 6 [in Russian], Metallurgiya, Moscow (1959), p. 259.
É. G. Fel'dgandler and L. Ya. Savkina, “Effect of impurity elements and process additives on the corrosion resistance of steel 03Kh17N14M3,” Stal', No. 8, 77–79 (1986).
L. Ya. Savkina and É. G. Fel'dgandler, “Effect of boron on the properties of low-carbon steel 03Kh17N13M3,” in: Quality Steels and Alloys, Coll. Works [in Russian], Metallurgiya, Moscow (1978), pp. 51–53.
N. N. Rodin, A. V. Plaskeev, M. A. Dembrovskii, et al., “Development of methods of gamma-spectrometry for determining partial rates and mechanism of dissolution of multicomponent steels,” Zashchita Met., 9(4), 387–394 (1973).
V. A. Ul'yanin, Corrosion-Resistant Steels and Alloys [in Russian], Metallurgiya, Moscow (1991).
A. V. Plaskeev and É. G. Fel'dgandler, “Effect of copper, molybdenum and silicon on the electrochemical corrosion behavior of austenitic chromium-nickel steel,” Zashchita Met., 36(4), 375–383 (2000).
N. S. Neiman, Ya. M. Kolotyrkin, V. M. Knyazheva, et al., “Problem of electrochemical corrosion properties of molybdenum in acid media,” Dokl. Akad. Nauk SSSR, 216(6), 1331–1334 (1974).
A. V. Plaskeev, O. V. Kasparova, and Ya. M. Kolotyrkin, “Role of active surface centers in the process of dissolution of iron and its alloys in sulfuric acid,” Zashchita Met., 20(1), 62–67 (1984).
W. B. Crow, J. R. Myers, and J. V. Jeffreys, “Anodic polarization behavior of Fe - Si alloys in sulfuric acid solution,” Corrosion, 28(3), 77–82 (1972).
A. V. Plaskeev and V. M. Knyazheva, “The role of molybdenum in the processes of passivation of alloys,” Zashchita Met., 31(1), 42–47 (1995).
A. M. Sukhotin (ed.), A Handbook on Electrochemistry [in Russian], Khimiya, Leningrad (1981).
É. G. Fel'dgandler, L. A. Sachina, L. Ya. Savkina, et al., “Corrosion-resistant steel, Inv. Certif. No. 1686027,” Otkr. Izobr., No. 39 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fel'dgandler, É.G., Plaskeev, A.V. Effect of Si and Cr Additives on Electrochemical Corrosion and Mechanical Properties of Austenitic Steel. Metal Science and Heat Treatment 45, 376–384 (2003). https://doi.org/10.1023/B:MSAT.0000009785.61892.eb
Issue Date:
DOI: https://doi.org/10.1023/B:MSAT.0000009785.61892.eb