Abstract
We studied the corrosion and corrosion-mechanical resistance of new austenitic high-nitrogen 12Kh18AG18Sh steel for the retaining rings of turbogenerators in aqueous solutions containing chlorides and copper (II) cations. A significant decrease in the corrosion resistance of this steel (P constitutes 0.52–14.50 mm/year) and in its resistance to corrosion cracking and corrosion-fatigue fracture in CuCl2 solutions was established. We also calculated the coefficients of linear parts of the kinetic diagrams of fatigue fracture of the steel under study in air with a humidity of 40% and in 22% NaCl and CuCl2 solutions.
Similar content being viewed by others
REFERENCES
G. Stein, M. Wagner, and L. Hentz, “Investigation of crack formation on the inner diameter of a retaining ring,” in: Proc. Generator Retaining Ring Workshop (Miami, Fla., December 8–9, 1997) (1997), pp. 3.1–3.21.
O. I. Balyts'kyi, Modern Materials for Powerful Turbogenerators [in Ukrainian], Karpenko Physicomechanical Institute, Ukrainian Academy of Sciences, Lviv (1999).
H. Feichtinger, G. Stein, and I. Hucklenbroich, “Case history of a 18Mn-18Cr retaining ring affected by stress corrosion cracks,” in: Proc. Generator Retaining Ring Workshop (Miami, Fla., December 8–9, 1997) (1997), pp. 1.1–1.29.
R. Crudelli, C. Rinaldi, L. Rossi, et al., “Case history of a 18Mn-18Cr retaining ring affected by stress corrosion cracks after 33500 operation hours “Motor & Generator Predictive Maintenance & Refurbishment”,” in: Proc. CIGRE/EPRI 1997 European Colloquium, Florence, Italy (1997), p. 5.
MR 185-86. Strength Analysis and Tests. Methods of Tests for Tendency towards Corrosion Cracking of Steels and Alloys in Liquid Media [in Russian], VNIIMASh, Moscow (1986).
S. I. Mikitishin and M. O. Levitskii, “A technique of making a crack in a cyclically deformed material,” Zavod. Lab., 40, No. 4, 474–475 (1974).
O. I. Balyts'kyi, “Two methods of studying the effect of hydrogen on the crack growth rate and the character of fracture of high-strength steels,” Fiz.-Khim. Mekh. Mater., 34, No. 4, 113–120 (1998).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Balyts'kyi, O.I., Krokhmal'nyi, O.O. & Ripei, I.V. Stress-Corrosion Fracture of 12Kh18AG18Sh Steel in Chloride-Containing Media with Copper Cations. Materials Science 39, 629–633 (2003). https://doi.org/10.1023/B:MASC.0000023501.28238.1f
Issue Date:
DOI: https://doi.org/10.1023/B:MASC.0000023501.28238.1f