Skip to main content
Log in

Geochemistry of Rare Earth Elements in the Ocean

  • Published:
Lithology and Mineral Resources Aims and scope Submit manuscript

Abstract

This work briefly outlines modern ideas on geochemistry of rare earth elements (REE) in the ocean. Sources of REE and chemical properties of these elements, which govern their migration ability in natural processes, are considered. The REE behavior in the river water–seawater mixing zone is analyzed. The fractionation of dissolved and suspended REE in oceanic water in both aerobic and anaerobic conditions is also considered. It is shown that the variability of REE composition in pelagic sediments reflects the fractionation of these elements in the oceanic water as a consequence of material differentiation in the ocean. The REE distribution in terrigenous, authigenic, hydrothermal, and biogenic constituents of sediments, such as clay, bone debris, barite, phillipsite, Fe–Mn oxyhydroxides (ferromanganese nodules and micronodules), Fe–Ca hydroxo-phosphate, diatoms, and foraminifers, is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  • Addy, S.K., Rare Earth Element Patterns in Manganese Nodules and Micronodules from Northwest Atlantic, Geochim. Cosmochim. Acta, 1979, vol. 43,no. 7, pp. 1105–1115.

    Google Scholar 

  • Balashov, Yu.A., Geokhimiya redkozemel'nykh elementov (Geochemistry of Rare Earth Elements), Moscow: Nauka, 1976.

    Google Scholar 

  • Balashov, Yu.A. and Lisitsyn, A.P., Migration of Rare Earth Elements in the Ocean, in Okeanologicheskie issledovaniya, (Oceanic Investigations), Moscow: Nauka, 1968, no. 18, pp. 213–282.

    Google Scholar 

  • Baturin, G.N., Tambiev, S.B., and Lyapunov, S.M., Rare Earth Elements in the Biogenic Phosphates from the Oceanic Bottom, Geokhimiya, 1986, vol. 24,no. 11, pp. 1636–1643.

    Google Scholar 

  • Bau, M., Scavenging of Dissolved Yttrium and Rare Earths by Precipitating Iron Oxyhydroxide: Experimental Evidence for Ce Oxidation, Y-Ho Fractionation and Lanthanide Tetrad Effect, Geochim. Cosmochim. Acta, 1999, vol. 63,no. 1, pp. 67–77.

    Google Scholar 

  • Bau, M. and Dulski, P., Comparing Yttrium and Rare Earths in Hydrothermal Fluids from the Mid-Atlantic Ridge: Implications for Y and REE Behavior during Near-Vent Mixing and for the Y/Ho Ratio of Proterozoic Seawater, Chem. Geol., 1999, vol. 155, pp. 77–90.

    Google Scholar 

  • Bau, M., Möller, P., and Dulski, P., Yttrium and Lanthanides in Eastern Mediterranean Seawater and Their Fractionation during Redox-Cycling, Mar. Chem., 1997, vol. 56,nos. 1/2, pp. 123–131.

    Google Scholar 

  • Bertram, C.J. and Elderfield, H., The Geochemical Balance of Rare Earth Elements and Neodymium Isotopes in the Oceans, Geochim. Cosmochim. Acta, 1993, vol. 57, pp. 1957–1986.

    Google Scholar 

  • Bogdanov, Yu.A., Gorshkov, A.I., Gurvich, E.G., Bogdanova, O.Yu., Dubinin, A.V., and Yansa, L.F., Ferromanganese Crusts and Nodules from Guyots of the Northwestern Pacific, Geokhimiya, 1998, vol. 36,no. 5, pp. 518–531 [Geochem. Int. (Engl. Transl.), 1998, vol. 36, no. 5, pp. 455–466].

    Google Scholar 

  • Boynton, W.V., Cosmochemistry of the Rare Earth Elements: Meteorite Studies, in Rare Earth Element Geochemistry. Developments in Geochemistry, Henderson, P., Ed., Amsterdam: Elsevier, 1984, pp. 63–114.

    Google Scholar 

  • Cronan, D., Underwater Minerals, London: Academic Press, 1980. Translated under the title Podvodnye mineral'nye mestorozhdeniya, Moscow: Mir, 1982.

    Google Scholar 

  • De Baar, H.J.W., German, C.R., Elderfield, H., and van Gaans, P., Rare Earth Element Distributions in Anoxic Waters of the Cariaco Trench, Geochim. Cosmochim. Acta, 1988, vol. 52, pp. 1203–1219.

    Google Scholar 

  • Douville, E., Charlou, J.L., Oelkers, E.H., Bienvenu, P., Jove Colon, C.F., Donval, J.P., Fouquet, Y., Prieur, D., and Appriou, P., The Rainbow Vent Fluids (36°14′N, MAR): The Influence of Ultramafic Rocks and Phase Separation on Trace Metal Content in Mid-Atlantic Ridge Hydrothermal Fluids, Chem. Geol., 2002, vol. 184, pp. 37–48.

    Google Scholar 

  • Dubinin, A.V., Formation of Nodules in the Guatemalan Basin: Evidence from Rare Earth Elements, Geokhimiya, 1996, vol. 34,no. 12, pp. 1210–1219 [Geochem. Int. (Engl. Transl.), 1996, vol. 34, no. 12, pp. 1090–1098].

    Google Scholar 

  • Dubinin, A.V., Ferromanganese Crust on Pelagic Sediments: Geochemistry and Formation Condition, Geokhimiya, 1998, vol. 36,no. 11, pp. 1152–1163 [Geochem. Int. (Engl. Transl.), 1998, vol. 36, no. 11, pp. 1041–1051].

    Google Scholar 

  • Dubinin, A.V., Geochemistry of Rare Earth Elements in Oceanic Phillipsites, Litol. Polezn. Iskop., 2000, vol. 35,no. 2, pp. 124–131 [Lithol. Miner. Resour. (Engl. Transl.), vol. 35, no. 2, pp. 101–108].

    Google Scholar 

  • Dubinin, A.V., Geochemistry of Fe-Ca Hydroxophosphates in Pelagic Sediments: Origin and Compositional Evolution in the Course of Diagenesis, Geokhimiya, 2001, vol. 39,no. 6, pp. 645–657 [Geochem. Int. (Engl. Transl.), 2001, vol. 39, no. 6, pp. 585–596].

    Google Scholar 

  • Dubinin, A.V. and Rozanov, A.G., Geochemistry of Rare Earth Elements and Thorium in Sediments and Ferromanganese Nodules of the Atlantic Ocean, Litol. Polezn. Iskop., 2001, vol. 36,no. 3, pp. 311–323 [Lithol. Miner. Resour. (Engl. Transl.), 2001, vol. 36, no. 3, pp. 268–279].

    Google Scholar 

  • Dubinin, A.V. and Strekopytov, S.V., Geochemistry of Rare Earth Elements during the Formation of Ferromanganese Nodules in the Peru Basin of the Pacific, Litol. Polezn. Iskop., 1994, vol. 29,no. 4, pp. 17–32.

    Google Scholar 

  • Dubinin, A.V. and Strekopytov, S.V., Behavior of Rare Earth Elements during the Leaching of Oceanic Sediments, Geokhimiya, 2001, vol. 39,no. 7, pp. 762–772 [Geochem. Int. (Engl. Transl.), 2001, vol. 39, no. 7, pp. 692–701].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N., Micronodules from the Guatemala Basin: Geochemistry of Rare Earth Elements, Litol. Polezn. Iskop., 1995, vol. 30,no. 5, pp. 473–479 [Lithol. Miner. Resour. (Engl. Transl.), 1995, vol. 30, no. 5, pp. 428–432].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N., Differential Mobility of Iron Oxyhydroxides in Processes of Micro-and Macronodule Formation with the Guatemala Basin in the Pacific as Example, Dokl. Akad. Nauk, 1996, vol. 348,no. 1, pp. 100–103 [Dokl. Earth Sci. (Engl. Transl.), 1996, vol. 348, no. 4, pp. 615–618].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N., Geochemistry of Rare Earth Elements in Micro-and Macronodules from the Pacific Bioproductive Zone, Litol. Polezn. Iskop., 2000a, vol. 35,no. 1, pp. 25–39 [Lithol. Miner. Resour. (Engl. Transl.), 2000, vol. 35, no. 1, pp. 19–31].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N., Geochemistry of Rare Earth Elements in Ferromanganese Micro-and Macronodules from the Pacific Nonproductive Zone, Litol. Polezn. Iskop., 2000b, vol. 35,no. 6, pp. 586–604 [Lithol. Miner. Resour. (Engl. Transl.), 2000, vol. 35, no. 6, pp. 520–537].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N., Evolution of Sedimentation: A Study of Authigenic and Biogenic Phases in Pelagic Sediments of the Southern Basin, Pacific Ocean, Geokhimiya, 2001, vol. 39,no. 4, pp. 404–421 [Geochem. Int. (Engl. Transl.), 2001, vol. 39, no. 4, pp. 356–372].

    Google Scholar 

  • Dubinin, A.V. and Sval'nov, V.N, Geochemistry of Manganese Ore Process in the Ocean: Evidence from Rare-Earth Elements, Litol. Polezn. Iskop., 2003, vol. 38,no. 2, pp. 115–125 [Lithol. Miner. Resour. (Engl. Transl.), 2003, vol. 38, no. 2, pp. 91–100].

    Google Scholar 

  • Dubinin, A.V. and Volkov, I.I., Rare Earth Elements in Metalliferous Sediments of the East Pacific Rise, Geokhimiya, 1986, vol. 24,no. 5, pp. 645–662.

    Google Scholar 

  • Dubinin, A.V. and Volkov, I.I., Mechanism of the Accumulation of Rare Earth Elements in Metalliferous Sediments of the East Pacific Rise, Geokhimiya, 1988, vol. 26,no. 4, pp. 557–566.

    Google Scholar 

  • Dubinin, A.V., Skornyakova, N.S., Strekopytov, S.V., and Volkov, I.I., Geochemistry of Rare Earth Elements in Nodules and Associated Sediments in the Northern Equatorial Pacific, Litol. Polezn. Iskop., 1997, vol. 32,no. 2, pp. 199–211 [Lithol. Miner. Resour. (Engl. Transl.), 1997, vol. 32, no. 2, pp. 172–183].

    Google Scholar 

  • Dupre, B., Gaillardet, J., Rousseau, D., and Allegre, C., Major and Trace Elements of River-Born Material: The Congo Basin, Geochim. Cosmochim. Acta, 1996, vol. 60,no. 8, pp. 1301–1321.

    Google Scholar 

  • Elderfield, H. and Greaves, M.J., Negative Cerium Anomalies in the Rare Earth Element Patterns of Oceanic Ferromanganese Nodules, Earth Planet. Sci. Lett., 1981, vol. 55,no. 1, pp. 163–170.

    Google Scholar 

  • Elderfield, H. and Greaves, M.J., The Rare Earth Elements in Seawater, Nature (London), 1982, vol. 296,no. 5854, pp. 214–218.

    Google Scholar 

  • Elderfield, H. and Pagett, R., Rare Earth Elements in Ichthyoliths: Variations with Redox Conditions and Depositional Environment, Sci. Total Environment, 1986, vol. 49, Spec. Issue., pp. 175–197.

    Google Scholar 

  • Elderfield, H. and Sholkovitz, E.R., Rare Earth Elements in the Pore Waters of Reducing Nearshore Sediments, Earth Planet. Sci. Lett., 1987, vol. 82, pp. 280–288.

    Google Scholar 

  • Elderfield, H., Hawkesworth, C.J., Greaves, M.J., and Calvert, S.E., Rare Earth Element Geochemistry of Oceanic Ferromanganese Nodules and Associated Sediments, Geochim. Cosmochim. Acta, 1981a, vol. 45, pp. 513–528.

    Google Scholar 

  • Elderfield, H., Hawkesworth, C.J., Greaves, M.J., and Calvert, S.E., Rare Earth Element Zonation in Pacific Ferromanganese Nodules, Geochim. Cosmochim. Acta, 1981b, vol. 45,no. 7, pp. 1231–1234.

    Google Scholar 

  • Elderfield, H., Upstill-Goddard, R., and Sholkovitz, E.R., The Rare Earth Elements in Rivers, Estuaries, and Coastal Seas and Their Significance to the Composition of Ocean Water, Geochim. Cosmochim. Acta, 1990, vol. 54, pp. 971–991.

    Google Scholar 

  • Fagel, N., Andre, L., and Debrabant, P., Multiple Seawater-Derived Geochemical Signatures in Indian Oceanic Pelagic Clays, Geochim. Cosmochim. Acta, 1997, vol. 61,no. 5, pp. 989–1008.

    Google Scholar 

  • Feely, R.A., Baker, E.T., Marumo, K., Urabe, T., Ishibashi, J., Gendron, J., Lebon, G.T., and Okamura, K., Hydrothermal Plume Particles and Dissolved Phosphate over the Superfast-Spreading Southern East Pacific Rise, Geochim. Cosmochim. Acta, 1996, vol. 60,no. 13, pp. 2297–2323.

    Google Scholar 

  • German, C.R. and Elderfield, H., Rare Earth Elements in Saanich Inlet, British Columbia, a Seasonally Anoxic Basin, Geochim. Cosmochim. Acta, 1989, vol. 53, pp. 2561–2571.

    Google Scholar 

  • German, C.R. and Elderfield, H., Rare Earth Elements in the NW Indian Ocean, Geochim. Cosmochim. Acta, 1990, vol. 54, pp. 1929–1940.

    Google Scholar 

  • German, C.R., Klinkhammer, G.P., Edmond, J.M., Mitra, A., and Elderfield, H., Hydrothermal Scavenging of Rare-Earth Elements in the Ocean, Nature (London), 1990, vol. 345, pp. 516–518.

    Google Scholar 

  • Goldberg, D.E., Koide, M., Schmitt, R.A., and Smith, R.H., Rare-Earth Distributions in the Marine Environment, J. Geophys. Res., 1963, vol. 68,no. 14, pp. 4209–4217.

    Google Scholar 

  • Goldstein, S. and Jacobsen, S.B., Rare Earth Elements in River Waters, Earth Planet. Sci. Lett., 1988, vol. 89,no. 1, pp. 35–47.

    Google Scholar 

  • Greaves, M.J., Statham, P.J., and Elderfield, H., Rare Earth Element Mobilization from Marine Atmospheric Dust into Seawater, Mar. Chem., 1994, vol. 46, pp. 255–260.

    Google Scholar 

  • Greaves, M.J., Elderfield, H., and Sholkovitz, E.R., Aeolian Sources of Rare Earth Elements to the Western Pacific Ocean, Mar. Chem., 1999, vol. 68, pp. 31–37.

    Google Scholar 

  • Gromet, L.P., Dymek, R.F., Haskin, L.A., and Korotev, R.L., The “North American Shale Composite”: Its Compilation, Major and Trace Element Characteristics, Geochim. Cosmochim. Acta, 1984, vol. 48,no. 12, pp. 2469–2482.

    Google Scholar 

  • Guichard, F., Church, T.M., Treuil, M., and Jaffrezic, H., Rare Earth in Barites: Distribution and Effects on Aqueous Partitioning, Geochim. Cosmochim. Acta, 1979, vol. 43,no. 7, pp. 983–997.

    Google Scholar 

  • Gurvich, E.G., Metallonosnye osadki Mirovogo okeana (Metalliferous Sediments in the World Ocean), Moscow: Nauchnyi Mir, 1998.

    Google Scholar 

  • Gurvich, E.G., Lukashin, V.N., Lisitsyn, A.P., and Kurinov, A.D., Rare Earth Elements and Yttrium, in Geokhimiya elementovgidrolizatov (Geochemistry of Hydrolyzate Elements), Ronova, A.B., Ed., Moscow: Nauka, 1980, pp. 71–116.

    Google Scholar 

  • Guy, C., Daux, V., and Schott, J., Behaviour of Rare Earth Elements during Seawater Basalt Interactions in the Mururoa Massif, Chem. Geol., 1999, vol. 158, pp. 21–35.

    Google Scholar 

  • Høgdahl, O.T., Melsom, S., and Bowen, V.T., Neutron Activation Analysis of Lanthanide Elements in Sea Water, Advances in Chemistry Series, 1968, no. 73, pp. 308–325.

    Google Scholar 

  • Hoyle, J., Elderfield, H., Gledhill, A., and Greaves, M., The Behaviour of the Rare Earth Elements during Mixing of River and Sea Waters, Geochim. Cosmochim. Acta, 1984, vol. 48,no. 1, pp. 143–149.

    Google Scholar 

  • James, R.H., Elderfield, H., and Palmer, M.R., The Chemistry of Hydrothermal Fluids from the Broken Spur Site, 29° N Mid-Atlantic Ridge, Geochim. Cosmochim. Acta, 1995, vol. 59,no. 4, pp. 651–659.

    Google Scholar 

  • Kawabe, I., Ohta, A., Ishii, S., Tokumura, M., and Miyauchi, K., REE Partitioning between Fe-Mn Oxyhydroxide Precipitates and Weakly Acid NaCl Solutions: Convex Tetrad Effect and Fractionation of Y and Sc from Heavy Lanthanides, Geochem. J., 1999, vol. 33, pp. 167–179.

    Google Scholar 

  • Keasler, K.M. and Loveland, W.D., Rare Earth Elemental Concentrations in Some Pacific Northwest Rivers, Earth Planet. Sci. Lett., 1982, vol. 61, pp. 68–72.

    Google Scholar 

  • Kunzendorf, H., Gwozdz, R., Glasby, G.P., Stoffers, P., and Ranner, R.M., The Distribution of Rare Earth Elements in Manganese Micronodules and Sediments from the Equatorial and Southwest Pacific, Appl. Geochem., 1989, no. 4, pp. 183–193.

    Google Scholar 

  • Lerche, D. and Nozaki, Y., Rare Earth Elements of Sinking Particulate Matter in the Japan Trench, Earth Planet. Sci. Lett., 1998, vol. 159, pp. 71–86.

    Google Scholar 

  • Lisitsyn, A.P., Protsessy okeanskoi sedimentatsii (Processes of the Oceanic Sedimentation), Moscow: Nauka, 1978.

    Google Scholar 

  • Martin, J.M., Hogdahl, O., and Phillippot, J.C., Rare Earth Element Supply to the Ocean, J. Geophys. Res., 1976, vol. 81,no. 18, pp. 3119–3124.

    Google Scholar 

  • Masuda, A. and Ikeuchi, Y., Lanthanide Tetrad Effect Observed in Marine Environment, Geochem. J., 1979, vol. 13,no. 1, pp. 19–22.

    Google Scholar 

  • Masuzawa, T. and Koyama, M., Settling Particles with Positive Ce Anomalies from the Japan Sea, Geophys. Res. Lett., 1989, vol. 16,no. 6, pp. 503–506.

    Google Scholar 

  • McArthur, J.M. and Walsh, J.N., Rare-Earth Geochemistry of Phosphorites, Chem. Geol., 1984, vol. 47,no. 3/4, pp. 191–220.

    Google Scholar 

  • McLennan, S.M., Rare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary Processes, in Geochemistry and Mineralogy of Rare Earth Elements. Reviews in Mineralogy, 1989, vol. 21, pp. 169–200.

    Google Scholar 

  • McLennan, S.M., Rare Earth Element Geochemistry and the “Tetrad Effect,” Geochim. Cosmochim. Acta, 1994, vol. 58, pp. 2025–2033.

    Google Scholar 

  • Michard, A., Rare Earth Elements Systematics in Hydrothermal Fluids, Geochim. Cosmochim. Acta, 1989, vol. 53,no. 3, pp. 745–750.

    Google Scholar 

  • Michard, A., Albarede, F., Michard, G., Minster, J.F., and Charlou, J.L., Rare-Earth Elements and Uranium in High-Temperature Solutions from East Pacific Rise Hydrothermal Vent Field (13° N), Nature (London), 1983, vol. 303, pp. 795–797.

    Google Scholar 

  • Migdisov, A.A., Bogdanov, Yu.A., Lisitsyn, A.P., Gurvich, E.G., Lebedev, A.I., Lukashin, V.N., Gordeev, V.V., Girin, Yu.P., and Sokolova E.G. Geochemistry of Metalliferous Sediments, in Metallonosnye osadki yugo-vostochnoi chasti Tikhogo okeana (Metalliferous Sediments in the Southeastern Pacific Ocean), Smirnov, V.I., Ed., Moscow: Nauka, 1979, pp. 122–201.

    Google Scholar 

  • Migdisov, A.A., Balashov, Yu.A., Sharkov, I.V., Sherstennikov, O.G., and Ronov, A.B., Rare Earth Elements in the Major Lithologic Rock Types in the Sedimentary Cover of the Russian Platform, Geokhimiya, 1994, vol. 32,no. 6, pp. 789–803.

    Google Scholar 

  • Mitra, A., Elderfield, H., and Greaves, M.J., Rare Earth Elements in Submarine Hydrothermal Fluids and Plumes from the Mid-Atlantic Ridge, Mar. Chem., 1994, vol. 46, pp. 217–235.

    Google Scholar 

  • Moffett, J.W., Microbially Mediated Cerium Oxidation in Sea Water, Nature (London), 1990, vol. 345,no. 6274, pp. 421–423.

    Google Scholar 

  • Moffett, J.W. and Ho, J., Oxidation of Cobalt and Manganese in Sea Water via a Common Microbially Catalyzed Pathway, Geochim. Cosmochim. Acta, 1996, vol. 60,no. 18, pp. 3415–3424.

    Google Scholar 

  • Murphy, K. and Dymond, J., Rare Earth Element Fluxes and Geochemical Budget in the Eastern Equatorial Pacific, Nature (London), 1984, vol. 307,no. 5950, pp. 444–447.

    Google Scholar 

  • Ohta, A. and Kawabe, I., REE(III) Adsorption onto Mn Dioxide (δ-MnO2) and Fe Oxyhydroxide: Ce(III) Oxidation by δ-MnO2, Geochim. Cosmochim. Acta, 2001, vol. 65,no. 5, pp. 695–703.

    Google Scholar 

  • Ostroumov, E.A., Rare Earth Elements in the Deep-Water Sediments of the Black Sea, Dokl. Akad. Nauk SSSR, 1953, vol. 91,no. 5, pp. 1175–1178.

    Google Scholar 

  • Palmer, M.R., Rare Earth Elements in Foraminifera Tests, Earth Planet. Sci. Lett., 1985, vol. 73, pp. 285–298.

    Google Scholar 

  • Pattan, J.N., Manganese Micronodules: A Possible Indicator of Sedimentary Environments, Mar. Geol., 1993, vol. 113, pp. 331–344.

    Google Scholar 

  • Pattan, J.N., Colley, S., and Higgs, N.C., Behavior of Rare Earth Elements in Coexisting Manganese Macronodules, Micronodules and Sediments from the Central Indian Basin, Mar. Georesour. Geotechnol., 1994, vol. 12, pp. 283–295.

    Google Scholar 

  • Piper, D.Z., Rare Earth Elements in the Sedimentary Cycle: A Summary, Chem. Geol., 1974, vol. 14,no. 4, pp. 285–304.

    Google Scholar 

  • Piper, D.Z. and Graef, P., Gold and Rare Earth Elements in Sediments from the East Pacific Rise, Mar. Geol., 1974, vol. 17, pp. 287–297.

    Google Scholar 

  • Rachold, V., Alabyan, A., Hubberten, H.-W., Korotaev, V.N., and Zaitsev, A.A., Sediment Transport to the Laptev Sea-Hydrology and Geochemistry of the Lena River, Polar Res., 1996, vol. 15,no. 2, pp. 183–196.

    Google Scholar 

  • Rimskaya-Korsakova, M.N. and Dubinin, A.V., Rare Earth Elements in Sulfides from Submarine Hydrothermal Vents of the Atlantic Ocean, Dokl. Ross. Akad. Nauk, 2003, vol. 389,no. 5, pp. 672–676 [Dokl. Earth Sci. (Engl. Transl.), 2003, vol. 389A, no. 3, pp. 345–349].

    Google Scholar 

  • Rudnicki, M.D. and Elderfield, H., A., Chemical Model of the Buoyant Plume above the TAG Vent Field, 26 Degrees N, Mid-Atlantic Ridge, Geochim. Cosmochim. Acta, 1993, vol. 57, pp. 2939–2957.

    Google Scholar 

  • Savenko, A.V. The Simultaneous Deposition of Phosphorus and Iron Hydroxide Formed during the Mixing of Submarine Hydrothermal Solutions with Sea Water (Based on Experimental Data), Geokhimiya, 1995, vol. 33,no. 9, pp. 1383–1389.

    Google Scholar 

  • Schijf, J., De Baar, H.J.W., Wijbrans, J.R., and Landing, W.M., Dissolved Rare Earth Elements in the Black Sea, Deep-Sea Res., 1991, vol. 38,Suppl. 2, pp. S805–S823.

    Google Scholar 

  • Sherrell, R.M., Field, M.P., and Ravizza, G., Uptake and Fractionation of Rare Earth Elements on Hydrothermal Plume Particles at 9° 45′ N, East Pacific Rise, Geochim. Cosmochim. Acta, 1999, vol. 63,no. 11/12, pp. 2561–2571.

    Google Scholar 

  • Sholkovitz, E.R., The Geochemistry of Rare Earth Elements in the Amazon River Estuary, Geochim. Cosmochim. Acta, 1993, vol. 57, pp. 2181–2190.

    Google Scholar 

  • Sholkovitz, E.R., The Aquatic Chemistry of Rare Earth Elements in Rivers and Estuaries, Aquatic Geochem., 1995, vol. 1, pp. 1–34.

    Google Scholar 

  • Sholkovitz, E.R., Piepgras, D.J., and Jacobsen, S.B., The Pore Water Chemistry of Rare Earth Elements in Buzzards Bay Sediments, Geochim. Cosmochim. Acta, 1989, vol. 53, pp. 2847–2856.

    Google Scholar 

  • Sholkovitz, E.R., Shaw, T.J., and Schneider, D.L., The Geochemistry of Rare Earth Element in the Seasonally Anoxic Water Column and Porewaters of Chesapeake Bay, Geochim. Cosmochim. Acta, 1992, vol. 56, pp. 3389–3402.

    Google Scholar 

  • Sholkovitz, E.R., Church, T.M., and Arimoto, R., Rare Earth Element Composition of Precipitation, Precipitation Particles, and Aerosols, J. Geophys. Res., 1993, vol. 98,no. 11, pp. 20587–20599.

    Google Scholar 

  • Strekopytov, S.V. and Dubinin, A.V., Rare Earth Elements as Indicators of the Composition of Sedimentary Matter Provenances of the Ocean with the Transpacific Profile as Example, Litol. Polezn. Iskop., 1996, vol. 31,no. 4, pp. 438–444 [Lithol. Miner. Resour. (Engl. Transl.), 1996, vol. 31, no. 4, pp. 390–395].

    Google Scholar 

  • Strekopytov, S.V., Dubinin, A.V., and Volkov, I.I., The Behavior of Rare Earth Elements, Zirconium, and Hafnium in Sediments and Nodules of the Transpacific Profile, Geokhimiya, 1995, vol. 33,no. 7, pp. 985–997.

    Google Scholar 

  • Strekopytov, S.V., Dubinin, A.V., and Volkov, I.I., General Regularities in the Behavior of Rare Earth Elements in Pelagic Sediments of the Pacific Ocean, Litol. Polezn. Iskop., 1999, vol. 34,no. 2, pp. 133–145 [Lithol. Miner. Resour. (Engl. Transl.), 1999, vol. 34, no. 2, pp. 111–122].

    Google Scholar 

  • Stumm, W. and Morgan, J.J., Aquatic Chem., New York: John Wiley and Sons, 1981.

    Google Scholar 

  • Sverjensky, D.A., Europium Redox Equilibria in Aqueous Solution, Earth Planet. Sci. Lett., 1984, vol. 67, pp. 70–78.

    Google Scholar 

  • Sval'nov, V.N., Lyapin, A.B., and Novikova, Z.T., Manganese Micronodules: Communication 1. Global Characteristics and Distribution in Pelagic Sediments, Litol. Polezn. Iskop., 1991a, no. 3, vol. 26, pp. 3–20.

    Google Scholar 

  • Sval'nov, V.N., Lyapin, A.B., and Novikova, Z.T., Manganese Micronodules: Communication 2. Composition and Origin, Litol. Polezn. Iskop., 1991b, vol. 26,no. 4, pp. 32–50.

    Google Scholar 

  • Tachikawa, K., Jeandel, C., Vangriesheim, A., and Dupre, B., Distribution of Rare Earth Elements and Neodymium Isotopes in Suspended Particles of the Tropical Atlantic Ocean (EUMELI Site), Deep Sea Res., 1999, Part I, vol. 46, pp. 733–755.

    Google Scholar 

  • Taylor, S.R. and McLennan, S.M., The Continental Crust: Its Composition and Evolution, Oxford: Blackwell 1985. Translated under the title Kontinental'naya kora: ee sostav i evolyutsiya, Moscow: Mir, 1988.

    Google Scholar 

  • Tlig, S., Distribution des terres rares dans les fractions de sediments et nodules de Fe et Mn associes en l'Ocean Indien, Marine Geol., 1982, vol. 50, pp. 257–274.

    Google Scholar 

  • Tlig, S. and Steinberg, M., Distribution of Rare-Earth Elements (REE) in Size Fractions of Recent Sediments of the Indian Ocean, Chem. Geol., 1982, vol. 37, pp. 317–333.

    Google Scholar 

  • Toyoda, K., Nakamura, Y., and Masuda, A., Rare Earth Elements of Pacific Pelagic Sediments, Geochim. Cosmochim. Acta, 1990, vol. 54,no. 4, pp. 1093–1103.

    Google Scholar 

  • Volkov, I.I. and Yagodinskaya, T.A., The Transitional Group of Elements: Phosphorus, Rare Earth Elements, and Yttrium, in Litologiya i geokhimiya osadkov Tikhogo okeana (transokeanskii profil') (Lithology and Geochemistry of Sediments in the Pacific Ocean, Transpacific Profile), Kholodov, V.N., Ed., Moscow: Nauka, 1979, pp. 203–224.

    Google Scholar 

  • Volkov, I.I., Sokolov, V.S., and Fomina, L.S., Reactive Forms of Elements in Sediments along the Transpacific Profile, in Geokhimiya diageneza osadkov Tikhogo okeana (transokeanskii profil”) (Geochemistry of Sediment Diagenesis in the Pacific Ocean, Transpacific Profile), Ostroumov, E.A., Ed., Moscow: Nauka, 1980, pp. 6–21.

    Google Scholar 

  • Wildeman, T.R. and Haskin, L., Rare-Earth Elements in Ocean Sediments, J. Geophys. Res., 1965, vol. 70,no. 12, pp. 2905–2910.

    Google Scholar 

  • Uspenskaya, T.Yu. and Skornyakova, N.S., Tekstury i struktury okeanskikh zhelezomargantsevykh konkretsii i korok (Textures and Structures of Oceanic Ferromanganese Nodules and Crusts), Moscow: Nauka, 1991.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dubinin, A.V. Geochemistry of Rare Earth Elements in the Ocean. Lithology and Mineral Resources 39, 289–307 (2004). https://doi.org/10.1023/B:LIMI.0000033816.14825.a2

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:LIMI.0000033816.14825.a2

Keywords

Navigation