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Characterization of physico-chemical properties of the high-temperature superconductor and LaCoO3surfaces

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Abstract

This paper presents possible applications of thermal analysis and sorptomatic methods to study physico-chemical properties of the high-T csuperconductor Y1Ba2Cu3O7-x and perovskite LaCoO3. It is shown that both Y1Ba2Cu3O7-x and perovskite phase are highly sensitive to water vapour. Mechanism of adsorption of water on LaCoO3depends largely on time activation (t act). When the time of water vapour saturation was 0<t act<180 s, physisorption process was observed. In the case of longer times water vapour action, t act>180 s, chemical decomposition was observed.

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Authors and Affiliations

  1. Institute of Physics, Faculty of Fundamental Problems of Technology, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370, Wrocław, Poland

    G. W. Chądzyński

  2. Department of Physicochemistry of Solid Surface, Chemistry Faculty, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031, Lublin, Poland

    D. Sternik & P. Staszczuk

  3. Institute of Inorganic Technology and Mineral Fertilizers, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370, Wrocław, Poland

    B. Kucharczyk

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  1. G. W. Chądzyński
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  2. D. Sternik
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  3. P. Staszczuk
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  4. B. Kucharczyk
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Chądzyński, G.W., Sternik, D., Staszczuk, P. et al. Characterization of physico-chemical properties of the high-temperature superconductor and LaCoO3surfaces. Journal of Thermal Analysis and Calorimetry 78, 441–447 (2004). https://doi.org/10.1023/B:JTAN.0000046109.22907.54

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  • DOI: https://doi.org/10.1023/B:JTAN.0000046109.22907.54

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