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Effect of glass transition temperature of polymeric binders on properties ceramic materials

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Abstract

In the paper are presented the studies of the effect of glass transition temperature of new water-thinnable polymeric binders on the properties of ceramic materials obtained by die pressing. The parameters of ceramic samples comprising polymeric binders have been compared with those of samples comprising poly(vinyl alcohol) (PVA) — water-soluble binder. When using poly(acrylic-styrene) (AS), poly(acrylic-allyl) (AA) and poly(vinyl-allyl) (VA) water-thinnable binders, materials of greater density and mechanical strength were obtained in the green state as well as after sintering than those in the case of using PVA. The dependence of the chemical structure of the binders applied on the properties of samples such as the glass transition temperature and hydrophobic-hydrophilic balance of the copolymers has been discussed.

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Authors and Affiliations

  1. Faculty of Chemistry, Warsaw University of Technology ul. Noakowskiego 3, 00-664, Warsaw, Poland

    M. Szafran, P. Wisniewski & G. Rokicki

Authors
  1. M. Szafran
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  2. P. Wisniewski
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  3. G. Rokicki
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Correspondence to P. Wisniewski.

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Szafran, M., Wisniewski, P. & Rokicki, G. Effect of glass transition temperature of polymeric binders on properties ceramic materials. Journal of Thermal Analysis and Calorimetry 77, 319–327 (2004). https://doi.org/10.1023/B:JTAN.0000033216.99303.33

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  • DOI: https://doi.org/10.1023/B:JTAN.0000033216.99303.33

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