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Pyridine-type complexes of transition-metal halides

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Abstract

Manganese(II) chloride complexes with 3,4- and 3,5-lutidine have been prepared. The crystal symmetry and cell dimensions have been calculated on the basis of powder diffraction data. The compounds were characterised also by FT-IR spectrometry. The thermal decomposition of the complexes has been studied by thermogravimetry and DSC. By plotting densities vs. molar mass, the diagram obtained has correspondence to similar observations in other solid metal-lutidine complex systems.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Novi Sad, 21000, Novi Sad, Trg D. Obradovişa 3, Serbia Montenegro E-mail

    K. Mészáros Szécsényi

  2. Department of Inorganic Chemistry, Budapest University of Technology and Economics, 1521, Budapest, Hungary

    T. Wadsten & G. Liptay

  3. Research Group of Technical Analytical Chemistry of the Hungarian Academy of Sciences at the Institute of General and Analytical Chemistry, Budapest University of Technology and Economics, 1521, Budapest, Hungary

    A. Kovács

Authors
  1. K. Mészáros Szécsényi
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  2. T. Wadsten
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  3. A. Kovács
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  4. G. Liptay
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Corresponding author

Correspondence to K. Mészáros Szécsényi.

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Mészáros Szécsényi, K., Wadsten, T., Kovács, A. et al. Pyridine-type complexes of transition-metal halides. Journal of Thermal Analysis and Calorimetry 75, 965–974 (2004). https://doi.org/10.1023/B:JTAN.0000027190.32572.8b

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  • DOI: https://doi.org/10.1023/B:JTAN.0000027190.32572.8b

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