Skip to main content
SpringerLink
Log in

Study on Coordination Behaviour of Manganese Chloride with L-a-Histidine

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The reaction thermodynamic and kinetic equations for the non-reversible reactions are established. The enthalpy change of formation reaction of manganese(II) histidine (His) complex in water has been determined by microcalorimetry, using manganese chloride with L-a-histidine at 298.15-323.15 K. The standard enthalpy of formation of Mn(His)2 2+(aq) has been calculated. On the basis of experimental and calculated results, three thermodynamics parameters (the activation enthalpy, the activation entropy and the activation free energy), the rate constants, along with three kinetic parameters (the apparent activation energies, the pre-exponential constant and the reaction order) are obtained. The results show that the reaction easily takes place over the studied temperature range. The solid complex Mn(His)2Cl2·4H2O was prepared and characterized by IR and TG-DTG.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Simeonova and P. Stancheva, Nauchni Tr.-Plovdivski Uni., 12 (1974) 135.

    CAS  Google Scholar 

  2. L. P. Berezina, V. G. Samoilenko and A. I. Pozigun, Zh. Neorg. Khim., 18 (1973) 393.

    CAS  Google Scholar 

  3. H. Kroll, J. Am. Chem. Soc., 74 (1952) 2034.

    Article  CAS  Google Scholar 

  4. Q. Steven, C. Eur. Pat. Appl. E P. 308983 (Cl. A61K49/00), 29 Mar 1989.

  5. E. J. Tiezzi, Chem. Soc. Perkin Trans., 2 (1975) 769.

    Article  Google Scholar 

  6. D. G. Batry, V. G. Isak and S. V. Kilmininov, Koord. Khim., 13 (1987) 1376.

    Google Scholar 

  7. D. G. Batry, V. G. Isak, S. V. Kilmininov and Ch. T. T. Phuong, Izv. Akad. Nauk Mold. SSR, Ser. Bio. Khim. Nauk, (1986) 46.

  8. Z. Ciumik and T. Glowiak, Inorg. Chim. Acta., 44 (1980) 1249.

    Google Scholar 

  9. S. Chen, Sh. Gao, X. Yang, R. Hu and Q. Shi, J. Therm. Anal. Cal., 73 (2003) 967.

    Article  CAS  Google Scholar 

  10. B. Malecka, E. Drożdż-Cieśla and P. K. Olszewski, J. Therm. Anal. Cal., 74 (2003) 485.

    Article  CAS  Google Scholar 

  11. P. W. Atkins, Physical Chemistry, 5th Edition Freeman, New York 1994, p. C9.

    Google Scholar 

  12. S. L. Gao, Y. D. Hou and M. Ji, Thermochim. Acta, 351 (2000) 47.

    Article  CAS  Google Scholar 

  13. S. L. Gao, M. Ji and S. P. Chen, Acta Chim. Sinica (China), 59 (2001) 931.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Northwest University, Shaanxi key laboratory of Physico-Inorganic Chemistry, Xi'an Shaanxi, 710069, People's Republic of China E-mail

    G. Shengli, C. Sanping, L. Huanyong, H. Rongzu & S. Qizhen

Authors
  1. G. Shengli
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Sanping
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Huanyong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Rongzu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Qizhen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Shengli.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shengli, G., Sanping, C., Huanyong, L. et al. Study on Coordination Behaviour of Manganese Chloride with L-a-Histidine. Journal of Thermal Analysis and Calorimetry 75, 795–805 (2004). https://doi.org/10.1023/B:JTAN.0000027176.44701.69

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000027176.44701.69

Search

Navigation