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Intermolecular interactions and phase equilibria in nitrocellulose - s-diethyldiphenylurea system

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Abstract

Values of the Flory-Huggins interaction parameters c were predicted on the base of mixing enthalpy H M for nitrocellulose-s-diethyldiphenylurea system. The phase diagram of the system and the glass transition temperature of mixtures T g12 were estimated using calculated c parameters. The predicted glass transition temperatures were in accordance with values determined experimentally.

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References

  1. A. Książczak and T. Książczak, J. Therm. Anal. Cal., 54 (1998) 323.

    Article  Google Scholar 

  2. Yu. M. Mikhailov, N. V. Chukanov and V. S. Smirnov, Izv. Akad. Nauk. Ser. Khim., 3 (1999) 487.

    Google Scholar 

  3. B. W. Brodman, M. P. Devine and M. T. Gurbarg, J. Appl. Polym. Sci., 18 (1974) 943.

    Article  CAS  Google Scholar 

  4. A. Książczak and T. Wolszakiewicz, J. Therm. Anal. Cal., 67 (2002) 751.

    Article  Google Scholar 

  5. P. J. Flory, Principles of polymer chemistry, Cornel University Press, NY 1953.

    Google Scholar 

  6. D. Patterson, Macromolecules, 2 (1969) 606.

    Article  Google Scholar 

  7. O. R. Orwoll, Rubber Chem. Technol., 50 (1977) 451.

    CAS  Google Scholar 

  8. N. Binke, L. Rong, C. Xiangi, W. Yuan, H. Rongzu and Y. Qingsen, J. Therm. Anal. Cal., 58 (1999) 249.

    Article  CAS  Google Scholar 

  9. S. Newman, J. Polymer Sci., 13 (1954) 179.

    Article  CAS  Google Scholar 

  10. X. Lu and R. A. Weiss, Macromolecules, 25 (1992) 3242.

    Article  CAS  Google Scholar 

  11. J. Zhanning, Propell. Explos. Pyrot., 17 (1992) 34.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664, Warsaw, Poland

    A. Książczak, Teresa Książczak & M. Ostrowski

Authors
  1. A. Książczak
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  2. Teresa Książczak
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  3. M. Ostrowski
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Książczak, A., Książczak, T. & Ostrowski, M. Intermolecular interactions and phase equilibria in nitrocellulose - s-diethyldiphenylurea system. Journal of Thermal Analysis and Calorimetry 74, 575–581 (2003). https://doi.org/10.1023/B:JTAN.0000005196.74550.8f

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  • DOI: https://doi.org/10.1023/B:JTAN.0000005196.74550.8f

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