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Phase relations in the system SbVO5-Sb3V2Mo3O21 in solid-state and in the atmosphere of air

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Abstract

It has been established by XRD, DTA and TG methods that phases of solid solution type of MoO3 in SbVO5 are formed in the system V2O5-MoO3-a-Sb2O4. The Mo6+ ions are incorporated into the crystal lattice of SbVO5 instead of both Sb5+ and V5+, while the charge compensation occurs by a formation of cation defects (□) at Sb5+ and V5+. The phases Sb1-6x □ xV1-6x □ xMo10xO5 are stable in the solid-state up to 690±10°C and the limit of solubility of MoO3 in SbVO5 does not exceed 20.00 mol%.

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  1. Institute of Chemistry and Environment Protection, Technical University of Szczecin, Al. Piastow 42, 71-065, Szczecin, Poland

    Elżbieta Flipek

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  1. Elżbieta Flipek
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Flipek, E. Phase relations in the system SbVO5-Sb3V2Mo3O21 in solid-state and in the atmosphere of air. Journal of Thermal Analysis and Calorimetry 74, 477–483 (2003). https://doi.org/10.1023/B:JTAN.0000005183.52150.4e

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  • DOI: https://doi.org/10.1023/B:JTAN.0000005183.52150.4e

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