Skip to main content
SpringerLink
Log in

Thermodynamic interpretation of three-parametric equation; Part I. New from of equation

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Thermodynamic interpretation of three-parametric equation connecting conversion degree (a) with temperature (T) was presented. One proved that thermal decomposition process of chemically defined compounds (CuSO4·5H2O, PhN(CH3)2·HCl) in dynamic conditions for 5 heating rates may be described by transformed three-parametric equation including equilibrium conversion degree.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Reference

  1. M. E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Strey, H. L. Anderson, A. Kemmler, R. Keuleers, J. Janssens, H. O. Desseyn, Chao-Rui Li, Tong B. Tang, B. Roduit, J. Málek and T. Mitsuhashi, Thermochim. Acta, 355 (2000) 125 (Part A).

    Article  CAS  Google Scholar 

  2. M. Maciejewski, Thermochim. Acta, 355 (2000) 145 (Part B).

    Article  CAS  Google Scholar 

  3. S. Vyazovkin, Thermochim. Acta, 355 (2000) 155 (Part C).

    Article  CAS  Google Scholar 

  4. A. K. Burnham, Thermochim. Acta, 355 (2000) 165 (Part D).

    Article  CAS  Google Scholar 

  5. B. Roduit, Thermochim. Acta, 355 (2000) 171 (Part E).

    Article  CAS  Google Scholar 

  6. J. R. MacCallum and J. Tanner, Nature, 225 (1970) 1127.

    Article  CAS  Google Scholar 

  7. P. Holba and J. Šesták, Z. Phys. Chem., Neue Folge, 80 (1972) 1.

    CAS  Google Scholar 

  8. J. Šesták, Měěení termofyzikálních vlasností pevných látek, Academia Praha, 1982.

  9. J. Błażejowski, Thermochim. Acta, 48 (1981) 109.

    Article  Google Scholar 

  10. J. Błażejowski, Thermochim. Acta, 76 (1984) 359.

    Article  Google Scholar 

  11. J. Błażejowski, J. Rak and M. Gutowski, J. Thermal Anal., 43 (1995) 45.

    Google Scholar 

  12. A. Mianowski, J. Therm. Anal. Cal., 60 (2000) 79.

    Article  CAS  Google Scholar 

  13. A. Mianowski, J. Therm. Anal. Cal., 59 (2000) 747.

    Article  CAS  Google Scholar 

  14. A. Mianowski, J. Therm. Anal. Cal., 63 (2001) 765.

    Article  CAS  Google Scholar 

  15. A. Mianowski, S. Błażewicz and Z. Robak, Carbon, 2003 (in press).

  16. A. Mianowski and T. Siudyga, J. Therm. Anal. Cal., 74 (2003) 623.

    Article  CAS  Google Scholar 

  17. A. Mianowski and R. Bigda, J. Therm. Anal. Cal., 74 (2003) 433.

    Article  CAS  Google Scholar 

  18. J. Błażejowski, J. Szychliński and R. Windorpska, Thermochim. Acta, 46 (1981) 147.

    Article  Google Scholar 

  19. J. Błażejowski, Thermochim. Acta, 68 (1983) 233.

    Article  Google Scholar 

  20. J. Łubkowski and J. Błażejowski, Thermochim. Acta, 121 (1987) 413.

    Article  Google Scholar 

  21. J. Błażejowski, Thermal Analysis Workshop, Zakopane, pp. 259–272, 15-19.04. 1996 (in Polish).

  22. A. Mianowski and R. Bigda, J. Therm. Anal. Cal., 2003 (in press).

  23. B. Scholl and R. Escales, Chem. Ber., 30 (1897) 3134–3136 (acc. Beilstein Information Systems - Crossfire plus Reactions).

    Article  CAS  Google Scholar 

  24. I. Barin, Thermochemical Data of Pure Substances, Vols. 1, 2, VCH Verlagsgesellschaft, Weinheim 1989.

    Google Scholar 

  25. J. Goworek and W. Stefaniak, Wiad. Chem., 46 (1992) 863 (in Polish).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Technology of Coal and Petroleum, Silesian University of Technology, 44-100, Gliwice, Poland

    A. Mianowski

  2. Institute for Chemical Processing of Coal, 41-803, Zabrze, Zamkowa 1, Poland

    R. Bigda

Authors
  1. A. Mianowski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Bigda
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mianowski, A., Bigda, R. Thermodynamic interpretation of three-parametric equation; Part I. New from of equation. Journal of Thermal Analysis and Calorimetry 74, 423–432 (2003). https://doi.org/10.1023/B:JTAN.0000005177.76846.74

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000005177.76846.74

Search

Navigation