Skip to main content
SpringerLink
Log in

An 227Ac-211Pb generator for test experiments of solution chemistry of element 114

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A simple and effective method has been developed for the continuous production of the short-lived isotope Pb as a homolog of element 114 on the principle of a radionuclide generator. The method is based on the initial sorption of 227Ac or 223Ra on a small cation-exchange column, with subsequent “milking” of 211Pb (36.1 m) by a mixture of HCl/CH3OH. The optimum conditions for the repeated separation of 211Pb from radionuclides strongly sorbed by the cation-exchanger (Ac, Th, Ra, Pu, TPE) have been determined. Possibilities of using the 211Pb generator for test experiments on the solution chemistry of element 114 have been shown. Advantages of aqueous alcohol HCl solutions for the isolation of 211Pb (element 114) are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. A. Lazarev, Yu. V. Lobanov, Yu. Ts. Oganessian, V. K. Utenkov, F. Sh. Abdullin, G. B. Buclanov, B. N. Gikal, S. Iliev, A. N. Mezentsev, A. N. Polyakov, I. M. Sedykh, I. V. Shirokovsky, V. G. Subbotin, A. M. Sukov, Yu. S. Tsyganov, V. E. Zhuchko, R. V. Lougheed, K. J. Moody, J. F. Wild, J. H.Y McQuoid, Phys. Rev. Lett., 73 (1994) 624.

    Article  CAS  Google Scholar 

  2. Yu. Ts. Oganessian, V. K. Utenkov, Yu. V. Lobanov, F. Sh. Abdullin, A. N. Polyakov, I. V. Shirokovsky, Yu. S. Tsyganov, G. G. Gulbekian, S. L. Bogomolov, B. N. Gikal, A. N. Mezentsev, S. Iliev, V. G. Subbotin, G. V. Buclanov, K. Subotic, M. G. Itkis, K. J. Moody, J. F. Wild, N. J. Stoyer, M. A. Stoyer, R. W. Lougheed, Phys. Rev. Lett., 83 (1999) 3154.

    Article  CAS  Google Scholar 

  3. Z. Szeglowski, H. Bruchertsifer, V. P. Domanov, B. Gleisberg, L. I. Guseva, M. Hussonnoia, G. S. Tikhomirova, I. Zvara, Yu. Ts. Oganessian, Radiochim. Acta, 51 (1990) 71.

    CAS  Google Scholar 

  4. Z. Szeglowski, H. Bruchertsifer, V. P. Domanov, B. Gleisberg, L. I. Guseva, M. Hussonnoia, G. S. Tikhomirova, I. Zvara, Yu. Ts. Oganessian, Radiokhimiya, 33 (1991) 90.

    Google Scholar 

  5. Z. Szeglowski, L. I. Guseva, Dinh-Thi Lien, V. P. Domanov, O. Constantinescu, G. S. Tikhomirova, H. Hussonnoia, Radiokhimiya, 35 (1993) 59.

    Google Scholar 

  6. Z. Szeglowski, L. I. Guseva, Dinh-Thi-Lien, V. P. Domanov, O. Constatinescu, M. Constantinescu, G. S. Tikhomirova, H. Hussonnoia, Radiokhimiya, 36 (1994) 263.

    CAS  Google Scholar 

  7. Z. Szeglowski, H. Bruchertseifer, V. B. Brudanin, G. V. Buclanov, O. Constantinescu, Dinh-Thi-Lien, V. P. Domanov, L. I. Guseva, M. Hussonnoia, G. S. Tikhomirova, I. Zvara, Yu. Ts. Oganessian, J. Radioanal. Nucl. Chem., 186 (1994) 353.

    Article  CAS  Google Scholar 

  8. K. H. Czerwinski, C. D. Kacher, K. E. Gregorich, T. M. Hamilton, N. J. Hannink, B. A. Kadkhodayan, S. A. Kreek, D. M. Lee, M. J. Nurmia, A. Turler, G. T. Seaborg, D. C. Hoffman, Radiochim. Acta, 64 (1994) 29.

    CAS  Google Scholar 

  9. D. Schumann, R. Dressler, S. Fischer, St. Taut, R. Binder, Z. Szeglowski, B. Kubica, L. I. Guseva, G. S. Tikhomirova, O. Constantinescu, V. P. Domanov, M. Constantinescu, Dinh-Thi-Lien, Yu.Ts. Oganessian, V. B. Brudanin, H. Bruchertseifer, Radiochim. Acta, 69 (1995) 35.

    CAS  Google Scholar 

  10. B. Wierczinski, J. Alstad, K. Eberhart, B. Eichler, H. Gaggeler, G. Herrmann, D. Jost, A. Nahler, M. Pense-Maskow, A. V. Reddy, G. Skarnemark, N. Trautmann, A. Turler, Radiochim. Acta, 69 (1995) 77.

    CAS  Google Scholar 

  11. Z. Szeglowski, H. Bruchertseifer, V. B. Brudanin, G. V. Buclanov, O. Constantinescu, Din-Thi-Lien, V. P. Domanov, L. I. Guseva, M. Hussonnoia, G. S. Tikhomirova, I. Zvara, Yu. Ts. Oganessia, J. Radioanal. Nucl. Chem., 212 (1996) 35.

    Article  CAS  Google Scholar 

  12. D. Schumann, S. Fischer, R. Dressler, St. Taut, H. Nitsche, N. Trautmann, M. Schadel, W. Bruchle, B. Schausten, A. V. Novgorodov, R. Misiak, B. Eichler, H. Gaggeler, D. Jost, A. Turler, H. Bruchertseifer, Radiochim. Acta, 72 (1996) 137.

    CAS  Google Scholar 

  13. C. D. Kacher, K. E. Gregorich, D. M. Lee, Y. Watanabe, B. Kadkhadayan, B. Wierczinski, M. R. Lane, E. R. Silwestrer, D. A. Keeney, M. Hendricks, N. J. Stoyer, J. Yang, M. Hsu, D. C. Hoffman, Radiochim. Acta, 75 (1996) 127; 135.

    CAS  Google Scholar 

  14. M. Schadel, W. Bruchle, B. Schausten, E. Schimpf, E. Jager, G. Wirth, R. Gunther, J. V. Kratz, W. Paulus, A. Seibert, P. Thorle, N. Trautmann, S. Zauner, D. Schumann, M. Andrassy, R. Misiak, K. E. Gregorich, D. C. Hoffman, D. M. Lee, E. R. Sylwester, Y. Nagame, Y. Oura, Radiochim. Acta, 77 (1997) 149.

    CAS  Google Scholar 

  15. B. Pfrepper, R. Pfrepper, A. B. Yakushev, S. N. Timokhin, I. Zvara, Radiochim. Acta, 77 (1997) 201.

    CAS  Google Scholar 

  16. Z. Szeglowski, L. I. Guseva, Dinh-Thi-Lien, V. P. Domanov, B. Kubica, G. S. Tikhomirova, O. Constantinescu, M. Constantinescu, A. V. Yakushev, J. Radioanal. Nucl. Chem., 228 (1998) 145.

    Article  CAS  Google Scholar 

  17. Z. Szeglowski, Dinh-Thi-Lien, L. I. Guseva, S. T. Timokhin, B. Kubica, G. S. Tikhomirova, J. Radioanal. Nucl. Chem., 251 (2002) 311.

    Article  CAS  Google Scholar 

  18. E. Strub, J. V. Kratz, A. Kronenberg, A. Nachler, P. Throle, S. Zauner, W. Bruchle, E. Jager, M. Schadel, B. Shausten, E. Schimpf, U. Kirbach, D. Schumann, D. Jost, A. Turler, M. Asai, Y. Nagame, M. Sakama, K. Tsukada, H. W. Gaggeler, P. Glatz, Radiochim. Acta, 88 (2000) 265.

    CAS  Google Scholar 

  19. G. Pfrepper, R. Pfrepper, A. Kronenberg, J. V. Kratz, W. Bruchle, M. Shade, Radiochim. Acta, 88 (2000) 273.

    CAS  Google Scholar 

  20. H. Haba, K. Tsukada, M. Asai, K. Akiyama, A. Toyoshima, S. Goto, I. Nishinaka, S. Ichikawa, Y. Nagame, M. Hirata, T. Yaita, H. Narita, J. K. Kratz, M. Schadel, Proc. Actinide-2001 Intern. Conf., Hayama, Japan, Nov. 4–9, 2001, Abstracts 1P11.

  21. R. W. Atcher, A. M. Friedman, J. R. Huizenga, R. P. Spencer, J. Radioanal. Nucl. Chem., 135 (1989) 215.

    Article  CAS  Google Scholar 

  22. L. I. Guseva, B. F. Myasoedov, G. S. Tikhomirova, L. I. Pavlenko, G. G. Babicheva, V. I. Koriakin, J. Radioanal. Chem., 13 (1973) 293.

    CAS  Google Scholar 

  23. L. I. Guseva, G. S. Tikhomirova, Radiokhimiya, 36 (1994) 51.

    CAS  Google Scholar 

  24. L. I. Guseva, G. S. Tikhomirova, Radiokhimiya, 27 (1986) 555.

    Google Scholar 

  25. I. Levin, Radiokhimiya, 21 (1979) 42.

    CAS  Google Scholar 

  26. L. I. Guseva, G. S. Tikhomirova, Radiokhimiya, 44 (2002) 154.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Vernadsky Institute of Geochemistry and Analytical Chemistry, Moscow, Russia

    L. I. Guseva & G. S. Tikhomirova

  2. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 117975, Moscow, Kosygin St., 19, Russia

    N. N. Dogadkin

Authors
  1. L. I. Guseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. S. Tikhomirova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Dogadkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guseva, L.I., Tikhomirova, G.S. & Dogadkin, N.N. An 227Ac-211Pb generator for test experiments of solution chemistry of element 114. Journal of Radioanalytical and Nuclear Chemistry 260, 167–172 (2004). https://doi.org/10.1023/B:JRNC.0000027076.41699.21

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JRNC.0000027076.41699.21

Keywords

Search

Navigation