Abstract
The electrophoretic method was recently developed for the determination of diffusion coefficients of ions in aqueous solution. By solving the Fick's second law in the presence of unlimited media and constant quantity of diffusing species we obtain a relationship between the diffusion coefficient and the standard deviation of the distribution profile. The diffusion coefficients of Cd(II), In(III), Zr(IV), Hf(IV), Pu(VI) and [InDTPA]2− in nitric acid solution were determined as well as the effective charge of In-DTPA complex at pH 4.50.
Similar content being viewed by others
References
N. K. Bulatov, A. B. Lundin, Thermodynamic of Nonequilibrium Physicochemical Processes, Chemistry, Moscow, 198, p. 279.
I. Cranc, The Mathematics of Diffusion, Claredon Press, Oxford, 1956, p. 10.
A. N. Priemyshev, G. D. Bontchev, G. A. Bojikov, B. A. Alikov, A. B. Salamatin, T. A. Furyaev, O. D. Maslov, M. V. Milanov, S. N. Dmitriev, JINR P13-2000-43, Dubna, 2000.
D. V. Filosofov, N. A. Lebedev, A. F. Novgorodov, G. D. Bontchev, G. Y. Starodub, P6-99-282, Dubna, 1999.
S. N. Dmitriev, Yu. Ts. Oganessian, G. Y. Starodub, S. V. Shishkin, G. V. Buklanov, Yu. P. Kharitonov, A. F. Novgorodov, Yu. V. Yushkevich, D. Newton, R. J. Talbot, Appl. Radiation Isototopes, 5 (1995) 307.
I. Korita, I. Dvorjak, V. Bogachkova, Electrochemistry, Mir, Moscow, 1975, p. 168.
A. N. Ermakov, I. N. Markov, V. K. Beliaeva, J. Inorg. Chem., 7 (1963) 1623.
V. Friehmelt, A. He, Z. Yang, G. Marx, Inorg. Chim. Acta, 109 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bozhikov, G.A., Bontchev, G.D., Ivanov, P.I. et al. Electrophoretic method for the determination of diffusion coefficients of ions in aqueous solutions*. Journal of Radioanalytical and Nuclear Chemistry 258, 645–648 (2003). https://doi.org/10.1023/B:JRNC.0000011763.86648.b5
Issue Date:
DOI: https://doi.org/10.1023/B:JRNC.0000011763.86648.b5