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Synthesis and Characterization of Polyaspartimides Containing Anisyl Moiety

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Abstract

New class of aromatic bismaleimides containing anisyl group were synthesized from bis(4-amino 3,5-dimethyl phenyl) anisyl methane and maleic anhydride via bismaleamic acid as an intermediate followed by cyclodehydration to bismaleimides. The structure was confirmed by FTIR, 1H-NMR and elemental analysis. Further, a series of polyaspartimides were synthesized by addition reaction of bismaleimide (BMDA) with various diamines. The polymers were characterized by IR and elemental analysis. The polymers exhibit good solubility in organic solvents such as NMP, DMF and DMSO. They exhibit good thermal stability. T g of polyaspartimides are in the range of 125–278 °C and T 10% weight loss are in the range of 398–476 °C.

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Authors and Affiliations

  1. Department of Chemistry, Anna University, Chennai, 600025, India

    R. Hariharan, G. Anuradha, S. Bhuvana & M. Saroja Devi

  2. Department of Chemistry, M.N.M. Jain Engineering college, Chennai, 600096, India

    M. Anitha

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  1. R. Hariharan
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  2. G. Anuradha
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  3. S. Bhuvana
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  4. M. Saroja Devi
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  5. M. Anitha
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Correspondence to M. Saroja Devi.

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Hariharan, R., Anuradha, G., Bhuvana, S. et al. Synthesis and Characterization of Polyaspartimides Containing Anisyl Moiety. Journal of Polymer Research 11, 239–245 (2004). https://doi.org/10.1023/B:JPOL.0000043411.34912.66

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  • DOI: https://doi.org/10.1023/B:JPOL.0000043411.34912.66

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