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Limiting Ionic Partial Molar Volumes of Cs+, Na+, (C4H9)4N+, Cl−, Br−, I−, BPh4 − in Aqueous Acetone at 298.15 K

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Abstract

Densities of CsX (X = Cl−, Br−, I−), NaBr, (C4H9)4NBr, and NaBPh4 in (0, 20, 40, 60 and 80) mass % acetone + water have been measured over the entire composition range at 298.15 K. The apparent and limiting partial molar volumes of the electrolytes and ions in their mixtures have been evaluated from these densities.

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REFERENCES

  1. F. J. Millero, in Water and Aqueous Solutions: Structure, Thermodynamics and Transport Processes, R. A. Horne, Ed. [Wiley (Interscience), New York, 1972].

    Google Scholar 

  2. L. Paivi, H. Pirila, and P. A. Ruostesuo, J Chem. Eng. Data 32, 303(1987).

    Google Scholar 

  3. J. A. Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents: Physical Properties and Methods of Purification, Techniques of Chemistry, Vol. II, 4th edn. [Wiley (Interscience), New York, 1986].

    Google Scholar 

  4. J. Bassett, R. C. Denny, G. H. Jeffrey, and J. Mendhara, Vogel's Textbook of Qualitative Inorganic Analysis, 4th edn. (Longman, New York, 1978), p. 74.

    Google Scholar 

  5. A. P. Kreshkov, Fundamentals of Analytical Chemistry, Vol. II, 3rd edn. (Khimiya, Moscow, 1970).

    Google Scholar 

  6. P. S. Nikam and A. B. Nikumbh. J. Chem.Eng. Data 47, 400(2002).

    Google Scholar 

  7. P. S. Nikam, B. S. Jagdale, A. B. Sawant, and Mehdi Hasan, Acoustic Lett. 22, 199(1999).

    Google Scholar 

  8. K. N. Marsh, Recommended Reference Materials for the Realisation of Physicochemical Properties (Blackwell Scientific, Oxford, U.K., 1987).

    Google Scholar 

  9. D. O. Masson, Phil. Mag. 8, 218(1929).

    Google Scholar 

  10. U. Sen, J. Phys. Chem. 80, 1566(1976).

    Google Scholar 

  11. B. E. Conway, R. E. Verrall, and J. E. Desnoyers, J. Chem. Soc. Faraday Trans. 62, 2738(1966).

    Google Scholar 

  12. R. Gopal and R. K. Shrivastava, J. Indian Chem. Soc. 40, 99(1963).

    Google Scholar 

  13. W.-Y. Wen and S. Saito, J. Phys. Chem. 68, 2639(1964).

    Google Scholar 

  14. C. Jolicoeur, R. R. Philip, G. Perron, P. A. Leduc, and J. E. Desnoyers, Can. J. Chem. 50, 3167(1972).

    Google Scholar 

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  1. P. G. Department of Physical Chemistry, M. S. G. College, Malegaon Camp, Pin, 423 105, India

    P. S. Nikam, Mehdi Hasan, R. P. Shewale & A. B. Sawant

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  1. P. S. Nikam
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  2. Mehdi Hasan
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  3. R. P. Shewale
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  4. A. B. Sawant
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Nikam, P.S., Hasan, M., Shewale, R.P. et al. Limiting Ionic Partial Molar Volumes of Cs+, Na+, (C4H9)4N+, Cl−, Br−, I−, BPh4 − in Aqueous Acetone at 298.15 K. Journal of Solution Chemistry 32, 987–995 (2003). https://doi.org/10.1023/B:JOSL.0000017063.77977.29

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  • DOI: https://doi.org/10.1023/B:JOSL.0000017063.77977.29

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