Abstract
The enthalpies of mixing of aqueous glucose solutions and six kinds of aqueous amino acid solutions (glycine, L-alanine, L-serine, L-valine, L-proline, and L-threonine) and their respective enthalpies of dilution have been determined at 298.15 K using flow microcalorimetry. The experimental data have been analyzed in terms of the McMillan–Mayer model to obtain the heterotactic interaction coefficients. The results have been interpreted from the point of view of solute–solute interactions.
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REFERENCES
P. H. Yancey, M. E. Clark, S. C. Hand, R. D. Bowlus, and G. N. Somero, Science 217, 1214(1982).
G. N. Somero, Amer. J. Physiol. 251, 197(1986).
S. N. Timasheff, Annu. Rev. Biophys. Biomol. Struct. 22, 67(1993).
M. M. Santoro, Y. Liu, S. M. A. Khan, L-X. Hou, and D. W. Bolen, Biochemistry 31, 5278(1992).
Y. Fujita and Y. Noda, Bull Chem. Soc. Jpn. 57, 1891(1984).
Y. Fujita and Y. Noda, Bull Chem. Soc. Jpn. 57, 2177(1984).
J. R. De and Xammar Ord, J. Bio. Phy. 27, 73(2001).
G. Castronuovo, V. Elia, M. Niccoli, and F. Velleca, Thermochim. Acta 389, 1(2002).
G. Castronuovo, V. Elia, and F. Velleca, J. Chem. Soc. Faraday. Trans. I 92, 4215(1996).
Xiaoling Ren, Yaming Ni, and Ruisen Lin, Thermochim. Acta 348, 19(2000).
Shuqin Li, Xingen Hu, and Ruisen Lin, Thermochim. Acta 342, 1(1999).
Shuang Shao, Xingen Hu, and Ruisen Lin, Thermochim. Acta 360, 93(2000).
Li Yu, Ruisen Lin, Xingen Hu, and Guiying Xu, J. Solution Chem. 32, 273(2003).
J. E. Desnoyers, Gperron, L. Avedikian, and J. P. Morel, J. Solution Chem. 5, 631(1976).
J. J. Kozak, W. S. Knight, and W. Kauzmann, J. Chem. Phys. 48, 675(1968).
W. G. McMillan and J. E. Mayer, J. Chem. Phys. 13, 276(1945).
B. Palecz, J. Solution Chem. 24, 537(1995).
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Liu, H., Lin, R. & Zhang, H. Enthalpic Interactions of Amino Acids with Glucose in Aqueous Solutions at 298.15 K. Journal of Solution Chemistry 32, 977–985 (2003). https://doi.org/10.1023/B:JOSL.0000017062.76672.4a
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DOI: https://doi.org/10.1023/B:JOSL.0000017062.76672.4a